화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.54, 126-136, October, 2017
DOI10.1016/j.jiec.2017.05.025  Export Citation
Synthesis of mesoporous PrxZr1-xO2- δ solid solution with high thermal stability for catalytic soot oxidation
Hongcheng Li1, Kongzhai Li1, 2, †, Xing Zhu1, Yunpeng Du2, Yonggang Wei1, 2, Kang Zhai1, and Hua Wang1, 2
  • 1State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Kunming University of Science and Technology, Kunming 650093, Yunnan, China, Korea
  • 2Faculty of Metallurgy and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, Yunnan, China
E-mail:
The fabrication of mesoporous PrxZr1-xO2-δ solid solutions with different Pr/Zr molar ratios is reported in the present work. Based on a systematic investigation, the anion of Zr precursor and template species are found to play the most important roles for the formation of mesoporous structure. The triblock copolymer Pluronic F127 template helps to generate porosity in the matrix by self-assembly into micelle, while the additional Cl-1 from Zr precursor can lead to the enhancement of the interaction between non-ionic micelles. The physicochemical properties of the obtained samples were studied by means of N2 sorption analysis, TEM, XRD, H2-TPR, O2-TPD and XPS technique. It is found that, compared with the nonmesoporous counterparts, the mesoporous PrxZr1-xO2-δ solid solutions possess much higher specific surface area (139 m2 g-1) and enhanced redox ability. Also, the ability to release oxygen is improved after aging at high temperature. For the catalytic soot oxidation, the fresh mesoporous Pr0.1Zr0.9O2-δ catalyst (calcinated at 500 °C) shows high activity in a loose contact condition (T50 = 399 °C). It should be highlighted that the T50 values over the three mesoporous PrxZr1-xO2-δ samples decrease by 8-24 °C after aging at 800 °C for 3 h. This suggests that the mesoporous PrxZr1-xO2-δ solid solution is an ideal candidate for catalytic application at high temperatures.
Keywords:Mesoporous oxides;Pr-Zr-O solid solution;Catalytic soot oxidation;Loose contact;Thermal stability
  1. Sadatlu MAA, Mozaffari N, Sol. Energy, 133, 24 (2016)
  2. Wang Y, Cui X, Li Y, Shu Z, Chen H, Shi J, Microporous Mesoporous Mater., 176, 8 (2013)
  3. Gong Y, Chen H, Chen Y, Cui X, Zhu Y, Zhou X, Shi J, Microporous Mesoporous Mater., 173, 112 (2013)
  4. Vadakkekara R, Chakraborty M, Parikh PA, J. Ind. Eng. Chem., 20(3), 767 (2014)
  5. Pak J, Yoo H, Microporous Mesoporous Mater., 185, 107 (2014)
  6. Vadakkekara R, Chakraborty M, Parikh PA, J. Ind. Eng. Chem., 20(3), 767 (2014)
  7. MacLachlan MJ, Coombs N, Ozin GA, Nature, 397(6721), 681 (1999)
  8. Meynen V, Cool P, Vansant EF, Microporous Mesoporous Mater., 125, 170 (2009)
  9. Pan JH, Zhao XS, Lee WI, Chem. Eng. J., 170(2-3), 363 (2011)
  10. Charalampides G, Vatalis KI, Apostoplos B, Ploutarch-Nikolas B, Procedia Econ. Finance, 24, 126 (2015)
  11. Pacheco AFC, Cuaspud JAG, Vargas CAP, J. Phys. Chem., 786, 12 (2017)
  12. Song ZX, Liu W, Nishiguchi H, Takami A, Nagaoka K, Takita Y, Appl. Catal. A: Gen., 329, 86 (2007)
  13. Logan AD, Shelef M, J. Mater. Res., 9, 468 (2011)
  14. Borchert Y, Sonstrom P, Wilhelm M, Borchert H, Baumer M, J. Phys. Chem., 112, 3054 (2008)
  15. Ran R, Weng D, Wu X, Fan J, Wang L, Wu X, J. Rare Earths, 29, 1053 (2011)
  16. Frank B, Schlogl R, Su DS, Sci. Technol., 47, 3026 (2013)
  17. Wanga Q, Sohn JH, Park SY, Choi JS, Lee JY, Chung JS, J. Ind. Eng. Chem., 16(1), 68 (2010)
  18. Atribak I, Bueno-Lopez A, Garcia-Garcia A, J. Catal., 259(1), 123 (2008)
  19. Fang P, Lu J, Xiao X, Luo M, J. Rare Earths, 26, 250 (2008)
  20. Nakatsuji T, Kunishige M, Li J, Hashimoto M, Matsuzono Y, Catal. Commun., 35, 88 (2013)
  21. Bellakki MB, Shivakumara C, Baidya T, Prakash AS, Vasanthacharya NY, Hegde MS, Mater. Res. Bull., 43(10), 2658 (2008)
  22. Du YP, Zhu X, Wang H, Wei YG, Li KZ, Trans. Nonferr. Met. Soc., 25, 1248 (2015)
  23. Du Y, Zhu X, Wang H, Wei Y, Li K, J. Energy Inst., 89, 745 (2016)
  24. Mogudi BM, Ncube P, Meijboom R, Appl. Catal. B: Environ., 198, 74 (2016)
  25. Wang H, Qu ZP, Xie HB, Maeda N, Miao L, Wang Z, J. Catal., 338, 56 (2016)
  26. Amini E, Rezaei M, Chin. J. Catal., 36, 1711 (2015)
  27. Said AEAA, El-Wahab MMMA, Soliman SA, Goda MN, Process Saf. Environ. Protect., 102, 370 (2016)
  28. Chowdhury IH, Chowdhury AH, Bose P, Mandal S, Naskar MK, RSC Adv., 6, 6038 (2016)
  29. Pal N, Bhaumik A, Adv. Colloid Interface Sci., 189-190, 21 (2013)
  30. Leontidis E, Curr. Opin. Colloid Interface Sci., 7, 81 (2002)
  31. Alexandridis P, Holzwarth JF, Langmuir, 13(23), 6074 (1997)
  32. Wu KC, Yamauchi Y, Hong CY, et al., Chem. Commun., 47, 5232 (2011)
  33. Yang ZL, Lu YF, Yang ZZ, Chem. Commun. 2270 (2009).
  34. Wan Y, Zhao DY, Chem. Rev., 107(7), 2821 (2007)
  35. Nakatsuji T, Kunishige M, Li J, Hashimoto M, Matsuzono Y, Catal. Commun., 35, 88 (2013)
  36. Wan Y, Ma JX, Fang M, Liu YT, J. Rare Earths, 21, 609 (2003)
  37. Luo MF, Yan ZL, Jin LY, J. Mol. Catal. A-Chem., 260(1-2), 157 (2006)
  38. Jin B, Wei Y, Zhao Z, Liu J, Jiang G, Duan A, Chin. J. Catal., 37, 923 (2016)
  39. Sun M, Wang L, Feng BN, Zhang ZG, Lu GZ, Guo Y, Catal. Today, 175(1), 100 (2011)
  40. Ivanov DV, Pinaeva LG, Sadovskaya EM, et al., Kinet. Catal., 52, 401 (2011)
  41. Lopez RR, Elizalde I, Mendez EER, et al., J. Sol-Gel Sci. Technol., 81, 214 (2017)
  42. Li KZ, Wang H, Wei YG, Yan DX, Int. J. Hydrog. Energy, 36(5), 3471 (2011)
  43. Vaz CAF, Wang HQ, Ahn CH, Henrich VE, Baykara MZ, Schwendemann TC, Pilet N, Albers BJ, Schwarz UD, Zhang LH, Zhu Y, Wang J, Altman EI, Surf. Sci., 603, 291 (2009)
  44. Liu J, Zhao Z, Wang JQ, Xu CM, Duan AJ, Jiang GY, Yang Q, Appl. Catal. B: Environ., 84(1-2), 185 (2008)
  45. Zhang ZL, Han D, Wei SJ, Zhang YX, J. Catal., 276(1), 16 (2010)
  46. Zhou Y, Xu C, Sheng Y, Zhu Q, Chen Y, Lu H, RSC Adv., 5, 91734 (2015)
  47. Venkataswamy P, Jampaiah D, Rao KN, Reddy BM, Appl. Catal. A: Gen., 488, 1 (2014)
  48. Aneggi E, de Leitenburg C, Trovarelli A, Catal. Today, 181(1), 108 (2012)
  49. Fino D, Bensaid S, Piumetti M, Russo N, Appl. Catal. A: Gen., 509, 75 (2016)
  50. Aneggi E, de Leitenburg C, Trovarelli A, in: Trovarelli A, Fornasiero P, (Eds.), Catalysis by Ceria and Related Materials, 2nd ed., Imperial College Press, London, 2013 p. 565.
  51. Wagloehner S, Kureti S, Appl. Catal. B: Environ., 125, 158 (2012)
  52. Iojoiu E, Bassou B, Guilhaume N, Farrusseng D, Desmartinchomel A, Lombaert K, Bianchi D, Mirodatos C, Catal. Today, 137, 103 (2008)
  53. Liu S, Wu XD, Liu W, Chen WM, Ran R, Li M, Weng D, J. Catal., 337, 188 (2016)
  54. Wang L, Fang SQ, Feng NJ, Wan H, Guan GF, Chem. Eng. J., 293, 68 (2016)
  55. Fino D, Russo N, Saracco G, Speechia V, J. Catal., 217(2), 367 (2003)
  56. Bueno-Lopez A, Appl. Catal. B: Environ., 146, 1 (2014)
  57. Tang XF, Li YG, Huang XM, Xu YD, Zhu HQ, Wang JG, Shen WJ, Appl. Catal. B: Environ., 62(3-4), 265 (2006)