화학공학소재연구정보센터
Journal of Physical Chemistry A, Vol.101, No.27, 4973-4978, 1997
Cmhn+ Reactions with H and H-2 - An Experimental-Study
We report measurements of the reactions of a number of hydrocarbon ions with atomic and molecular hydrogen made using a selected ion flow tube (SIFT) operating at room temperature. Results, including branching ratios and rate coefficients, are reported for CmHn+ ions (m = 2-6, n = 0-9). Highly unsaturated hydrocarbon ions undergo mainly H atom abstraction reactions with H-2 forming CmHn+1+ + H products. More saturated ions are unreactive. Two types of reactions occur for H atoms : H atom transfer to give CmHn-1+ + H-2 (if exothermic) and association (to give CmHn+1+).