화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.55, 128-139, November, 2017
DOI10.1016/j.jiec.2017.06.037  Export Citation
Malachite green removal from aqueous solutions using fibrous cellulose sulfate prepared from medical cotton waste: Comprehensive batch and column studies
Majid Baghdadi†, Bahram Alipour Soltani†, and Mohammad Nourani†
  • Department of Environmental Engineering, Graduate Faculty of Environment, University of Tehran, Tehran, Iran
E-mail:, ,
In this study, high capacity and regenerable fibrous cellulose sulfate was prepared by chemical modification of medical cotton waste and its performance was evaluated for malachite green removal through batch and fixed-bed experiments. Equilibrium was achieved after 30 min of mixing (t90%: 3.5 min at 200 mg L-1). The equilibrium and kinetic data were fitted to Redlich.Peterson and Dubinin. Radushkevich models (qm: 960 mg g-1) and pseudo-second-order model, respectively. Breakthrough data were predicted by Thomas model. The breakthrough volume was increased by increasing flow rate due to decrease in mass transfer resistance. Adsorbent was regenerated using NaCl solution (4% w/v).
Keywords:Fibrous cellulose sulfate;Malachite green;Medical cotton waste;Fixed-bed column;Adsorption
  1. Mohammadi A, Daemi H, Barikani M, Int. J. Biol. Macromol., 69, 447 (2014)
  2. Roosta M, Ghaedi M, Daneshfar A, Sahraei R, Asghari A, Ultrason. Sonochem., 21(1), 242 (2014)
  3. Zheng H, Qi J, Jiang R, Gao Y, Li X, J. Environ. Manage., 162, 232 (2015)
  4. Ai LH, Huang HY, Chen ZL, Wei X, Jiang J, Chem. Eng. J., 156(2), 243 (2010)
  5. Baek MH, Ijagbemi CO, Se-Jin O, Kim DS, J. Hazard. Mater., 176(1-3), 820 (2010)
  6. Srivastava S, Sinha R, Roy D, Aquat. Toxicol, 66(3), 319 (2004)
  7. Kushwaha AK, Gupta N, Chattopadhyaya MC, J. Saudi Chem. Soc., 18(3), 200 (2014)
  8. Jamshidi M, Ghaedi M, Dashtian K, Hajati S, Bazrafshan AA, Ultrason. Sonochem., 32, 119 (2016)
  9. Azad FN, Ghaedi M, Dashtian K, Hajati S, Pezeshkpour V, Ultrason. Sonochem., 31, 383 (2016)
  10. Bulut E, Ozacar M, Sengil IA, Microporous Mesoporous Mater., 115(3), 234 (2008)
  11. Robinson T, McMullan G, Marchant R, Nigam P, Bioresour. Technol., 77(3), 247 (2001)
  12. Rajabi M, Mirza B, Mahanpoor K, Mirjalili M, Najafi F, Moradi O, Sadegh H, Shahryari-ghoshekandi R, Asif M, Tyagi I, Agarwal S, Gupta VK, J. Ind. Eng. Chem., 34, 130 (2016)
  13. Mirzajani R, Ahmadi S, J. Ind. Eng. Chem., 23, 171 (2015)
  14. Elsaesser A, Howard CV, Adv. Drug Deliv. Rev., 64(2), 129 (2012)
  15. Hristozov D, Malsch I, Sustainability, 1(4), 1161 (2009)
  16. Han RP, Wang YF, Yu WH, Zou WH, Shi H, Liu HM, J. Hazard. Mater., 141(3), 713 (2007)
  17. Mittal A, J. Hazard. Mater., 133(1-3), 196 (2006)
  18. Carpenter AW, de Lannoy CF, Wiesner MR, Environ. Sci. Technol., 49(9), 5277 (2015)
  19. Batmaz R, Mohammed N, Zaman M, Minhas G, Berry RM, Tam KC, Cellulose, 21(3), 1655 (2014)
  20. John Manley RS, J. Polym. Sci. A: Polym. Chem., 9, 1025 (1971)
  21. Zhang L, Yi H, J. Environ. Sci., 26, 1203 (2014)
  22. Chuah TG, Jumasiah A, Azni I, Katayon S, Choong SYT, Desalination, 175(3), 305 (2005)
  23. Musyoka SM, Mittal H, Mishra SB, Ngila JC, Int. J. Biol. Macromol., 65, 389 (2014)
  24. Gusmao KAG, Gurgel LVA, Melo TMS, Gil LF, Dyes Pigment., 92(3), 967 (2012)
  25. Kumar V, Goel NK, Bhardwaj YK, Sabharwal S, Varshney L, Sep. Sci. Technol., 47(13), 1937 (2012)
  26. Thomas HC, J. Am. Chem. Soc., 66(10), 1664 (1944)
  27. Bohart GS, Adams EQ, J. Chem. Soc, 42(7) (1920)
  28. Chen SH, Yue QY, Gao BY, Li Q, Xu X, Fu KF, Bioresour. Technol., 113, 114 (2012)
  29. Gutierrez-Segura E, Colin-Cruz A, Solache-Rios M, Fall C, Water Air Soil Pollut., 223(8), 5505 (2012)
  30. Katsigiannis A, Noutsopoulos C, Mantziaras J, Gioldasi M, Chem. Eng. J., 280, 49 (2015)
  31. Han RP, Wang Y, Zou WH, Wang YF, Shi H, J. Hazard. Mater., 145(1-2), 331 (2007)
  32. Tumsek F, Avci O, J. Chem. Eng. Data, 58(3), 551 (2013)
  33. Sabnis RW, Handbook of Acid-Base Indicators, first ed., CRC Press, New York, 2008.
  34. Chowdhury S, Mishra R, Saha P, Kushwaha P, Desalination, 265(1-3), 159 (2011)
  35. Ahmad MA, Alrozi R, Chem. Eng. J., 171(2), 510 (2011)
  36. Santhi T (2011). 10.1016/j.arabjc.2011.06.004.
  37. Weng CH, Lin YT, Tzeng TW, J. Hazard. Mater., 170(1), 417 (2009)
  38. Gao Y, Xu S, Yue Q, Wu Y, Gao B, J. Taiwan Inst. Chem. Eng., 000, 1 (2016)
  39. Nandi BK, Goswami A, Purkait MK, J. Hazard. Mater., 161(1), 387 (2009)
  40. Charumathi D, Das N, Desalination, 285, 22 (2012)
  41. Wang WQ, Li MY, Zeng QX, Sep. Purif. Technol., 149, 16 (2015)
  42. Crittenden JC, Trussell RR, Hand DW, Howe KJ, Tchobanoglous G, MWH’s Water Treatment: Principles and Design, John Wiley & Sons, 2012.
  43. Gupta S, Babu BV, Bioresour. Technol., 100(23), 5633 (2009)
  44. Malik R, Ramteke DS, Wate SR, Waste Manage., 27(9), 1129 (2007)
  45. Vimonses V, Lei SM, Jin B, Chowd CWK, Saint C, Chem. Eng. J., 148(2-3), 354 (2009)
  46. Ghaedi M, Ansari A, Habibi MH, Habibi AR, J. Ind. Eng. Chem., 20(1), 17 (2014)
  47. Liu X, Zhang Z, Shi W, Zhang Y, An S, Zhang L, Dispers J, Sci. Technol, 36(4), 462 (2015)
  48. Gautam RK, Rawat V, Banerjee S, Sanroman MA, Soni S, Singh SK, Chattopadhyaya MC, J. Mol. Liq., 212, 227 (2015)
  49. Bekci Z, Ozveri C, Seki Y, Yurdakoc K, J. Hazard. Mater., 154(1-3), 254 (2008)
  50. Rahman IA, Saad B, Shaidan S, Rizal ESS, Bioresour. Technol., 96(14), 1578 (2005)
  51. Dahri MK, Kooh MRR, Lim LBL, J. Environ. Chem. Eng., 2(3), 1434 (2014)
  52. Gupta N, Kushwaha AK, Chattopadhyaya MC, Arab. J. Chem., 9, S707 (2016)
  53. Szydłowska-Czerniak A, Szłyk E, Food Chem., 81(4), 613 (2003)
  54. Jayanthi S, Eswar NKR, Singh SA, Chatterjee K, Madras G, Sood AK, RSC Adv., 6(2), 1231 (2016)
  55. Sekhar CP, Kalidhasan S, Rajesh V, Rajesh N, Chemosphere, 77(6), 842 (2009)