Transparent Lamellar Porous Material and Its Greatly Reduced Dielectric Constant

Lili Liu; Cuijiao Zhao; Yawen Huang; Xiaonan Wei; Hongtao Yu; Junxiao Yang

Macromolecular Research, Vol.25, No.10, 989-993, October, 2017

DOI10.1007/s13233-017-5141-6 Export Citation

Transparent Lamellar Porous Material and Its Greatly Reduced Dielectric Constant

Lili Liu¹, Cuijiao Zhao^{1, 2}, Yawen Huang^{1, †}, Xiaonan Wei^{1, 2}, Hongtao Yu², and Junxiao Yang^{1, †}

¹State Key Laboratory Cultivation Base for Nonmetal Composite and Functional Materials, Southwest University of Science and Technology, Mianyang 621010, P. R. China
²School of Material Science and Engineering, Southwest University of Science and Technology, Mianyang 621010, P. R. China

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One trend for low dielectric materials is to reach low dielectric constant values at as low porosity as possible. In this work, a lamellar porous material was prepared by spin-coating of poly(vinyl alcohol) (PVA)/manganese dioxide (MnO2) nanosheet composited film, followed by cross-linking of PVA and removing nanosheets. FTIR, XRD and TGA measurement results demonstrate that the templates were almost completely removed. SEM image shows that the etched PVA film has a lamellar porous structure. Dielectric test results indicate that at the porosity of only 17.5%, the dielectric constant of porous PVA is reduced to approximately half that of neat cross-linked PVA. The serial model shows a good consistence with experimental dielectric constant value. This explains well the high efficiency of lamellar porous structure in reducing dielectric constant.

Keywords:low dielectric;nanocomposites;porous materials;lamellar;templating method

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[Referenced By]

[1] Volksen W, Miller RD, Dubois G, Chem. Rev., 110(1), 56 (2010)

[2] Ree M, Yoon JW, Heo KY, J. Mater. Chem., 16, 685 (2006)

[3] Seino M, Wang WD, Lofgreen JE, Puzzo DP, Manabe T, Ozin GA, J. Am. Chem. Soc., 133(45), 18082 (2011)

[4] Zhang H, Du QG, Zhou J, Zhang XL, Wang HT, Zhong W, Eur. Polym. J., 44, 1095 (2008)

[5] Fukumaru T, Fujigaya T, Nakashima N, Polym. Chem., 3, 369 (2012)

[6] Fu GD, Kang ET, Yuan ZL, Neoh KG, Lai DM, Huan ACH, Adv. Funct. Mater., 15, 315 (2005)

[7] He ZW, Sun WX, Liu XQ, Xu DY, Gou J, Wang YY, Eur. Phys. J. B, 48, 463 (2005)

[8] Fisher I, Kaplan WD, Eizenberg M, J. Appl. Phys., 95, 5762 (2004)

[9] Si JJ, Ono H, Uchida K, Nozaki S, Morisaki H, Appl. Phys. Lett., 79, 3140 (2001)

[10] Xia HJ, Wan GP, Yang F, Wang JS, Bai Q, Mater. Lett., 180, 19 (2016)

[11] Israel S, Gurevitch I, Silverstein MS, Polymer, 72, 453 (2015)

[12] Jiang JL, Chen ZG, Duanmu CS, Gu YX, Chen J, Ni LN, Mater. Lett., 132, 425 (2014)

[13] Reddy KR, Lee KP, Gopalan AI, Showkat AM, Polym. J., 38, 349 (2006)

[14] Alix S, Follain N, Tenn N, Alexandre B, Bourbigot S, Soulestin J, Marais S, J. Phys. Chem., 116, 4937 (2012)

[15] Bartczak Z, Rozanski A, Richert J, Eur. Polym. J., 61, 274 (2014)

[16] Tong WS, Zhang YH, Yu L, Luan XL, An Q, Zhang Q, Lv FZ, Chu PK, Shen B, Zhang ZL, J. Phys. Chem., 118, 10567 (2014)

[17] Khan MU, Reddy KR, Snguanwongchai T, Haque E, Gomes VG, Colloid Polym. Sci., 294, 1599 (2016)

[18] Han SJ, Lee HI, Jeong HM, Kim BK, Raghu AV, Reddy KR, J. Macromol. Sci.-Phys., 53, 1194 (2014)

[19] Son DR, Raghu AV, Reddy KR, Jeong HM, J. Macromol. Sci.-Phys., 55, 1099 (2016)

[20] Choi SH, Kim DH, Raghu AV, Reddy KR, Lee HI, Yoon KS, Jeong HM, Kim BK, J. Macromol. Sci.-Phys., 51, 197 (2012)

[21] Hassan M, Reddy KR, Hague E, Minett AI, Gomes VG, J. Colloid Interface Sci., 410, 43 (2013)

[22] Hassan M, Reddy KR, Haque E, Faisal SN, Ghasemi S, Compos. Sci. Technol., 98, 1 (2014)

[23] Lee YR, Kim SC, Lee H, Jeong HM, Raghu AV, Reddy KR, Kim BK, Macromol. Res., 19(1), 66 (2011)

[24] Ma Y, Luo J, Suib SL, Chem. Mater., 11, 1972 (1999)

[25] Sakai N, Ebina Y, Takada K, Sasaki T, J. Phys. Chem. B, 109(19), 9651 (2005)

[26] Wang H, Zhang JJ, Hang XD, Zhang XD, Xie JF, Pan BC, Xie Y, Angew. Chem.-Int. Edit., 54, 1195 (2015)

[27] Abdulrahman HB, Kolataj K, Lenczewski P, Krajczewski J, Kudelski A, Appl. Surf. Sci., 388, 704 (2016)

[28] Cakici M, Reddy KR, Alonso-Marroquin F, Chem. Eng. J., 309, 151 (2017)

[29] Li XG, McKenna GB, Miquelard-Garnier G, Guinault A, Sollogoub C, Regnier G, Rozanski A, Polymer, 55(1), 248 (2014)

[30] Boland CS, Barwich S, Khan U, Coleman JN, Carbon, 99, 280 (2016)

[31] Das P, Schipmann S, Malho J, Zhu BL, Klemradt U, Walther A, ACS Appl. Mater. Interfaces, 5, 3738 (2013)

[32] Walther A, Bjurhager I, Malho JM, Ruokolainen J, Berglund L, Ikkala O, Angew. Chem.-Int. Edit., 49, 6448 (2010)