화학공학소재연구정보센터
Chemical Physics Letters, Vol.687, 9-13, 2017
Similarity law and critical properties in ionic systems
Using molecular simulations, we determine the locus of ideal compressibility, or Zeno line, for a series of ionic compounds. We find that the shape of this thermodynamic contour follows a linear law, leading to the determination of the Boyle parameters. We also show that a similarity law, based on the Boyle parameters, yields accurate critical data when compared to the experiment. Furthermore, we show that the Boyle density scales linearly with the size-asymmetry, providing a direct route to establish a correspondence between the thermodynamic properties of different ionic compounds. (C) 2017 Elsevier B.V. All rights reserved.