We demonstrate a novel and universal strategy to significantly boost electrochemical performances of conducting polymer-based flexible supercapacitors via the relatively facile electrodeposition of Mo-Ni-P compounds. The fabricated Mo-Ni-P@polyaniline (PANI)@carbon fiber cloth (CFC) sandwiched hybrid, for instance, delivers 94.6% of specific capacitance retention from 1 to 40 mA cm(-2) and 92.3% of specific capacitance retention at a high current density of 40 mA cm(-2) after 2000 cycles, much greater than 56.8% and 58.3% for the uncoated PANI@CFC with Mo-Ni-P, respectively. With increasing the numbers for repeatedly alternate coating PANI and Mo-Ni-P layer by layer, the specific capacitances rise almost linearly. Simultaneously, the capacitance retentions maintain high levels at 40 mA cm(-2) after 2000 cycles. A remarkable decrease in the charge transfer resistance and a markedly enhanced hydrophilicity with coating Mo-Ni-P on the surface of PANI@CFC can be found, which can greatly facilitate the electron and electrolyte ion transfer processes and thereby bring with it improved supercapacitive performance. Likewise, the supercapacitive performances of polypyrrole and poly(3,4-ethylenedioxythiophene) can be significantly enhanced in comparison with their Mo-Ni-P uncoated counterparts. (C) 2017 Elsevier Ltd. All rights reserved.