Making efficient trifunctional non-precious metal catalysts for simultaneously catalyzing oxygen reduction reaction (ORR), oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) in same electrolyte is very important to bring energy conversion and storage systems into realities. Herein, hierarchical Co9S8 hollow microspheres had been designed and synthesized by a facile hydrothermal reaction at 140 degrees C (denoted as Co9S8 HMs-140). The properties and formation process of the Co9S8 HMs-140 were systematically investigated. Owing to the composition and structure features, the Co9S8 HMs-140 can be used as a trifunctional catalyst for ORR, OER and HER in the same alkaline electrolyte. The Co9S8 HMs-140 shows reasonable ORR and HER performance. Additionally, OER performance of the Co9S8 HMs-140 is superior to that of RuO2, such as a low onset potential (1.47 V vs. RHE) and high stability. Furthermore, due to the bifunctional OER and HER activity of the Co9S8 HMs-140, the Co9S8 HMs-140 affords an O-2 efficiency of 31 mmol h (1) and a H-2 efficiency of 62 mmol h (1) at 1.60 V in 1 M KOH solution under the given time range, exhibiting a 96% faradaic yield in the process of full water splitting to produce O-2 and H-2. The present work will provide a promising prospect for the development of multifunctional transition metal sulfides as effective electrocatalysts for sustainable energy systems. (C) 2017 Elsevier Ltd. All rights reserved.