Energy & Fuels, Vol.31, No.8, 8087-8094, 2017
Removal of Hydrogen Sulfide in Simulated Coke Oven Gas with Low Grade Iron Ore
The hydrogen sulfide (H2S) removal performance.of limonite in the presence.of coke oven gas (COG) components (H-2, CH4, CO, CO2, and H2O) has been studied in.a cylindrical flow-type quartz-made fixed-bed reactor at 300-800 degrees C under a high space velocity of 51,000 h(-1) to develop a novel hOt gas cleanup method. The H2S removal behavior by reduced limonite in He does not change at the temperatures examined. On the other hand, the breakthrough curves in 50%H-2/He depend on the temperature; and high performance is found at lower temperatures. An investigation of the breakthrough curves of H2S in the presence of COG,components at 300-600 degrees C reveals that the addition of 30%CH4-14 to 50%H-2/He does not influence the performance below 500 degrees C, whereas the coexistence of 5%CO with 50%H-2/He drastically clecreaseS the H2S removal ability of reduCed,limonite. In addition, the breakthrough curves in 5%CO2 coexisting with 50%H-2/30%CH4/5% CO/He are similar to those of 50%H-2/30%CH4/5%CO/He. However, the addition of 5%H2O to 5Q%H-2/30%CH4/5%CO/He dramatically improves the H2S removal performance of reduced limonite. Similar tendencies are observed in simulated COG (50%H-2/30%CH4/5%CO2/5%H2O/He). Furthermore, the H2S breakthrough curve strongly depends 'on the space velocity.