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Journal of Applied Electrochemistry, Vol.47, No.9, 1083-1090, 2017
Columnar structure and electrochemical anisotropy of a nickel-based superalloy fabricated via laser solid forming
Electrochemical anisotropy has drawn substantial attention in the fields of electrochemical dissolution and corrosion, and it is related to the surface energy levels in a single-phase alloy. Here, laser solid forming (LSF) Inconel 718 alloy was found to be a multi-phase alloy with a strong fiber texture. Its horizontal section (HS), in which secondary phases have a tube-like distribution, mainly consists of the (001) crystallographic plane, while a vertical section (VS) with a strip-like secondary phase, consists of the (001) crystal zone. The HS was first measured to be more electrochemically stable but it has a higher anodic dissolution rate than VS in 10 wt% NaNO3. Contrast analysis indicates that the electrochemical anisotropy can primarily be attributed to the columnar structure. Therefore, researchers should be very careful when using a surface energy model to predict the electrochemical anisotropy of a highly textured alloy. For convenience, the red-colored secondary phases are continuous. Actually, they are continuous or discontinuous. (Color figure online). [GRAPHICS] .