Journal of Crystal Growth, Vol.476, 25-30, 2017
Nanoscale zinc silicate from phytoliths
We report a faster, less expensive method of producing zinc silicate nanoparticles. Such particles are used in high volume to make phosphors and anti-corrosion coatings. The approach makes use of phytoliths ( plant rocks), which are microscopic, amorphous, and largely silicate particles embedded in plants, that lend themselves to being easily broken down into nanoparticles. Nanoparticles of Zn2SiO4 were produced in a two stage process. In the refinement stage, plant residue, mixed with an appropriate amount of ZnO, was heated in an argon atmosphere to a temperature exceeding 1400 degrees C for four to six hours and then heated in air at 650 degrees C to remove excess carbon. TEM shows 50-100 nm nanoparticles. Raman scattering indicates that only the -Zn2SiO4 crystalline phase was present. X-ray analysis indicated pure rhombohedral R (3) over bar phase results from using rice/wheathusks. Both samples luminesced predominantly at 523 nm when illuminated with X-rays or UV laser light.