Undoped and Co2+ doped FeS2 thin films (Co compositions are 1 to 5 mole%) were deposited on indium tin oxide glass substrate by a single step electrochemical deposition (ECD) method at low temperature (70 degrees C). Glancing angle X-ray diffraction (GAXRD) and Raman spectra showed that as-deposited undoped and Co2+ doped FeS2 thin films have a cubic pyrite structure without any trace of orthorhombic marcasite phase. Co2+ doping does not affect the cubic structure of FeS2 thin films with a strong (111) plane preferred orientation in all the doped thin films. The height profiling of 3 mole% of Co2+ doped FeS2 thin film by atomic force microscopy revealed a smooth surface with uniform distribution of particles and low roughness values. Co2+ (3, 4 and 5 mole%) doped thin films show a strong absorption peak in the higher wavelength region. Magnetic measurement reveals that Co2+ doping into the FeS2 lattice induces ferromagnetism. The Co2+ in FeS2 thin films acts as the acceptor and the original p-type conductivity is retained. Solar light irradiation with the intensity of 100 mW/cm(2) on Co2+ (3 mole%) doped FeS2 thin film cell resulted in a power conversion efficiency of 5.42%. (C) 2017 The Electrochemical Society.