EDTA-Na2-assisted synthesis of rod-like titanate-TiO2 composite architectures with enhanced visible-light-driven properties

Minh-Tri Nguyen-Le; Byeong-Kyu Lee; Dinh-Minh Tran

Journal of Industrial and Engineering Chemistry, Vol.56, 225-233, December, 2017

DOI10.1016/j.jiec.2017.07.015 Export Citation

EDTA-Na2-assisted synthesis of rod-like titanate-TiO2 composite architectures with enhanced visible-light-driven properties

Minh-Tri Nguyen-Le, Byeong-Kyu Lee^†, and Dinh-Minh Tran

Department of Civil & Environmental Engineering, University of Ulsan, Ulsan 680-749, Republic of Korea

E-mail:

A simple wet chemical method was developed to synthesize visible-light-driven titanate-TiO2 rod-like composites using ethylenediaminetetraacetic disodium salt (EDTA-Na2) as both template-directed modifier and nitrogen doping source. The synthesized heterojunctions exhibited both enhanced adsorption ability and photocatalytic activity for the degradation of methylene blue (MB) dye under visible light irradiation. EDTA-Na2 was found to alter the condensation pathway of the titanium precursor. This study also identified the different loading effects of EDTA-Na2 on the adsorption and photocatalytic degradation. ㆍO2 - was the dominant radical for MB photodegradation.

Keywords:Nitrogen doping;Ti3+ doped;Titanate;TiO2;EDTA-Na2

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[Referenced By]

[1] Meng ZH, Wang LJ, Li XX, Zhang GQ, Li HY, Int. J. Hydrog. Energy, 42(4), 2177 (2017)

[2] Zhang D, Zhang X, Ni X, Song J, Zheng H, Cryst. Growth Des., 7, 2117 (2007)

[3] Li C, Yang J, Yang P, Zhang X, Lian H, Lin J, Cryst. Growth Des., 8, 923 (2008)

[4] Wang LP, Chen LM, Mater. Charact., 69, 108 (2012)

[5] Nassoko D, Li YF, Wang H, Li JL, Li YZ, Yu Y, J. Alloy. Compd., 540, 228 (2012)

[6] Sohail M, Xue HL, Jiao QZ, Li HS, Khan K, Wang SS, Zhao Y, Mater. Res. Bull., 90, 125 (2017)

[7] Hunge YM, Mahadik MA, Moholkar AV, Bhosale CH, Appl. Surf. Sci., 420, 764 (2017)

[8] Shen HZ, Ie IR, Yuan CS, Hung CH, Appl. Catal. B: Environ., 195, 90 (2016)

[9] Nguyen-Le MT, Lee BK, Catal. Today (2017), doi:http://dx.doi.org/10.1016/j.cattod.2017.03.036.

[10] Binas V, Venieri D, Kotzias D, Kiriakidis G, J. Materiomics, 3, 3 (2017)

[11] Huang WC, Ting JM, Novel nitrogen-doped anatase TiO2 mesoporous bead photocatalysts for enhanced visible light response, Ceramics International.

[12] Xiong ZG, Zhao XS, J. Am. Chem. Soc., 134(13), 5754 (2012)

[13] Sauvet AL, Baliteau S, Lopez C, Fabry P, J. Solid State Chem., 177, 4508 (2004)

[14] Zhang P, Shao C, Zhang Z, Zhang M, Mu J, Guo Z, Liu Y, Nanoscale, 3, 2943 (2011)

[15] Chen XB, Liu L, Yu PY, Mao SS, Science, 331(6018), 746 (2011)

[16] Sahoo S, Arora AK, Sridharan V, J. Phys. Chem., 113, 16927 (2009)

[17] Kolen'ko YV, Kovnir KA, Gavrilov AI, Garshev AV, Frantti J, Lebedev OI, Churagulov BR, Van Tendeloo G, Yoshimura M, J. Phys. Chem. B, 110(9), 4030 (2006)

[18] Zhang Z, Goodall JBM, Brown S, Karlsson L, Clark RJH, Hutchison JL, Rehman IU, Darr JA, Dalton Trans., 39, 711 (2010)

[19] Zhu HY, Lan Y, Gao XP, Ringer SP, Zheng ZF, Song DY, Zhao JC, J. Am. Ceram. Soc., 127, 6730 (2005)

[20] Jackson AW, Shebanova O, Hector AL, McMillan PF, J. Solid State Chem., 179, 1383 (2006)

[21] Du H, Williams CT, Ebner AD, Ritter JA, Chem. Mater., 22, 3519 (2010)

[22] You W, Feng M, Zhan YM, Chen R, Zhan HB, Chem. Eng. J., 233, 360 (2013)

[23] Etacheri V, Michlits G, Seery MK, Hinder SJ, Pillai SC, ACS Appl. Mater. Interfaces, 5, 1663 (2013)

[24] Kiatkittipong K, Iwase A, Scott J, Amal R, Chem. Eng. Sci., 93, 341 (2013)

[25] Nguyen-Le MT, Lee BK, Chem. Eng. J., 281, 20 (2015)

[26] Luo Z, Poyraz AS, Kuo CH, Miao R, Meng Y, Chen SY, Jiang T, Wenos C, Suib SL, Chem. Mater., 27, 6 (2015)

[27] Chenakin SP, Melaet G, Szukiewicz R, Kruse N, J. Catal., 312, 1 (2014)

[28] Lee SH, Yamasue E, Ishihara KN, Okumura H, Appl. Catal. B: Environ., 93(3-4), 217 (2010)

[29] Qiu B, Zhou Y, Ma Y, Yang X, Sheng W, Xing M, Zhang J, Sci. Rep., 5, 8591 (2015)

[30] Jaiswal R, Patel N, Kothari DC, Miotello A, Appl. Catal. B: Environ., 126, 47 (2012)

[31] Ren WJ, Ai ZH, Jia FL, Zhang LZ, Fan XX, Zou ZG, Appl. Catal. B: Environ., 69(3-4), 138 (2007)

[32] Zhao L, Chen XF, Wang XC, Zhang YJ, Wei W, Sun YH, Antonietti M, Titirici MM, Adv. Mater., 22(30), 3317 (2010)

[33] Rosseler O, Sleiman M, Montesinos VN, Shavorskiy A, Keller V, Keller N, Litter MI, Bluhm H, Salmeron M, Destaillats H, J. Phys. Chem. Lett., 4, 536 (2013)

[34] Etacheri V, Michlits G, Seery MK, Hinder SJ, Pillai SC, ACS Appl. Mater., 5, 1663 (2013)

[35] Irie H, Watanabe Y, Hashimoto K, J. Phys. Chem. B, 107(23), 5483 (2003)

[36] Asahi R, Morikawa T, Ohwaki T, Aoki K, Taga Y, Science, 293, 269 (2001)

[37] Sawyer DT, McKinnie JM, J. Am. Chem. Soc., 82, 4191 (1960)

[38] Wang CC, Ying JY, Chem. Mater., 11, 3113 (1999)

[39] Zhang Y, Wu ZF, Gao PF, Fang DQ, Zhang SL, J. Alloy. Compd., 704, 478 (2017)

[40] Gurulakshmi M, Selvaraj M, Selvamani A, Vijayan P, Rekha NRS, Shanthi K, Appl. Catal. A: Gen., 449, 31 (2012)

[41] Devi LG, Kavitha R, Appl. Catal. B: Environ., 140-141, 559 (2013)

[42] Nguyen-Le MT, Lee BK, RSC Adv., 6, 31347 (2016)