화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.56, 335-341, December, 2017
DOI10.1016/j.jiec.2017.07.029  Export Citation
A facile fabrication method and the boosted adsorption and photodegradation activity of CuO nanoparticles synthesized using a silk fibroin template
Jong Wook Kim1, Chang Seok Ki1, 2, In Chul Um3, and Young Hwan Park1, 2, †
  • 1Department of Biosystems and Biomaterials Science and Engineering, Seoul National University, Seoul 08826, Republic of Korea
  • 2Research Institute of Agriculture and Life Sciences, Seoul National University, Seoul 08826, Republic of Korea
  • 3Department of Bio-fibers and Materials Science, Kyungpook National University, Daegu 41566, Republic of Korea
E-mail:
Silk fibroin (SF)/CuO nanoparticles were formed from a precursor solution containing Cu2+, and SF in the presence of sodium dodecyl sulfate under alkali condition. Morphological, crystal and mesoporous structures of SF/CuO nanoparticles were characterized by varying preparation conditions. Based on the structural analysis results, a nanoparticle formation mechanism has been proposed and its photocatalytic degradation performance was evaluated with Congo Red. The hybrid nanoparticles containing 0.1% SF exhibited the highest Congo Red removal performance (128.30 mg/g) by both adsorption and photodegradation while the pure CuO nanoparticle showed a lower removal effect (109.02 mg/g).
Keywords:Copper oxide;Silk;fibroin;Nanoparticle;Photodegradation;Adsorption
  1. Gawande MB, Goswami A, Felpin FX, Asefa T, Huang XX, Silva R, Zou XX, Zboril R, Varma RS, Chem. Rev., 116(6), 3722 (2016)
  2. Gattinoni C, Michaelides A, Surf. Sci. Rep., 70, 424 (2015)
  3. Nguyen MA, Bedford NM, Ren Y, Zahran EM, Goodin RC, Chagani FF, Bachas LG, Knecht MR, ACS Appl. Mater. Interfaces, 7, 13238 (2015)
  4. Sang X, Zhang J, Wu T, Zhang B, Ma X, Peng L, Han B, Kang X, Liu C, Yang G, RSC Adv., 5, 67168 (2015)
  5. Meghana S, Kabra P, Chakraborty S, Padmavathy N, RSC Adv., 5, 12293 (2015)
  6. Su DW, Xie XQ, Dou SX, Wang GX, Sci. Rep., 4, 5753 (2014)
  7. Sheng W, Zhu G, Kaplan DL, Cao C, Zhu H, Lu Q, Nanotechnology, 26, 115603 (2015)
  8. Hong JM, Li J, Ni YH, J. Alloy. Compd., 481, 610 (2009)
  9. Li DP, Dai K, Lv JL, Lu LH, Liang CH, Zhu GP, Mater. Lett., 150, 48 (2015)
  10. Feng JT, Hou YH, Wang XY, Quan WL, Zhang JM, Wang YC, Li LC, J. Alloy. Compd., 681, 157 (2016)
  11. Mansour NB, El Mir L, J. Mater. Sci. Mater. Electron., 27, 11682 (2016)
  12. Konar S, Kalita H, Puvvada N, Tantubay S, Mahto MK, Biswas S, Pathak A, J. Catal., 336, 11 (2016)
  13. Fei X, Shao ZZ, Chen X, Nanoscale, 5, 7991 (2013)
  14. Xu XX, Yang H, Liu YN, CrystEngComm, 14, 5289 (2012)
  15. Song Y, Li X, Wei C, Fu J, Xu F, Tan H, Tang J, Wang L, Sci. Rep., 5, 8401 (2015)
  16. Yan DH, Yin GF, Huang ZB, Yang M, Liao XM, Kang YQ, Yao YD, Hao BQ, Han D, J. Phy. Chem. B, 113, 6047 (2009)
  17. Huang ZB, Yan DH, Yang M, Liao XM, Kang YQ, Yin GF, Yao YD, Hao BQ, J. Colloid Interface Sci., 325(2), 356 (2008)
  18. Duman F, Ocsoy I, Kup FO, Mater. Sci. Eng. C-Biomimetic Supramol. Syst., 60, 333 (2016)
  19. Xu Y, Wang H, Yu YF, Tian L, Zhao WW, Zhang B, J. Phys. Chem., 115, 15288 (2011)
  20. Liang YH, Shang L, Bian T, Zhou C, Zhang DH, Yu HJ, Xu HT, Shi Z, Zhang TR, Wu LZ, Tung CH, CrystEngComm, 14, 4431 (2012)
  21. Zou YW, Huang ZB, Wang Y, Liao XM, Yin GF, Gu JW, Colloids Surf. B: Biointerfaces, 102, 29 (2013)
  22. Fei X, Li W, Shao ZZ, Seeger S, Zhao DY, Chen X, J. Am. Chem. Soc., 136(44), 15781 (2014)
  23. Cheng C, Shao ZZ, Vollrath F, Adv. Funct. Mater., 18(15), 2172 (2008)
  24. Fei X, Jia MH, Du X, Yang YH, Zhang R, Shao ZZ, Zhao X, Chen X, Biomacromolecules, 14(12), 4483 (2013)
  25. Yan DH, Yin GF, Huang ZB, Li L, Liao XM, Chen XC, Yao YD, Hao BQ, Langmuir, 27(21), 13206 (2011)
  26. Fei X, Shao Z, Chen X, J. Mater. Chem., 1, 213 (2013)
  27. Sheng WQ, Liu J, Liu SS, Lu Q, Kaplan DL, Zhu HS, J. Mater. Chem., 2, 7394 (2014)
  28. Liu J, Deng M, Huang ZB, Yin GF, Liao XM, Gu JW, Colloids Surf. B: Biointerfaces, 107, 19 (2013)
  29. Singh DK, Mohan S, Kumar V, Hasan SH, RSC Adv., 6, 1218 (2016)
  30. Wu XL, Hou J, Li MZ, Wang JN, Kaplan DL, Lu SZ, Acta Biomater., 8, 2185 (2012)
  31. Singh DP, Ojha AK, Srivastava ON, J. Phys. Chem., 113, 3409 (2009)
  32. Ki CS, Gang EH, Um NC, Park YH, J. Membr. Sci., 302(1-2), 20 (2007)
  33. Yalcin E, Gedikli S, Cabuk A, Karahaliloglu Z, Demirbilek M, Bayram C, Sam M, Saglam N, Denkbas EB, Clean Technol., 17, 921 (2015)
  34. Zhou WT, Huang HT, Du S, Huo YD, He JX, Cui SZ, Appl. Surf. Sci., 345, 169 (2015)
  35. Gusain R, Kumar P, Sharma OP, Jain SL, Khatri OP, Appl. Catal. B: Environ., 181, 352 (2016)
  36. Wang X, Jia G, Yu Y, Gao Y, Zhang W, Wang H, Cao Z, Liu J, Quim. Nova, 38, 298 (2015)
  37. dos Santos SX, Cavalheiro ETG, J. Braz. Chem. Soc., 25, 1071 (2014)
  38. Pramanik A, Maiti S, Mahanty S, Dalton Trans., 44, 14604 (2015)
  39. Sudarsanam P, Hillary B, Mallesham B, Rao BG, Amin MH, Nafady A, Alsalme AM, Reddy BM, Bhargave SK, Langmuir, 32(9), 2208 (2016)
  40. Zhang YX, Kuang M, Wang JJ, CrystEngComm, 16, 492 (2014)
  41. Wen T, Wu X, Tan X, Wang X, Xu A, ACS Appl. Mater. Interfaces, 5, 3304 (2013)
  42. Cudennec Y, Lecerf A, Solid State Sci., 5, 1471 (2003)
  43. Zhang J, Feng HJ, Qin Q, Zhang GF, Cui YX, Chai ZZ, Zheng WJ, J. Mater. Chem., 4, 6357 (2016)
  44. Zhang ZP, Sun HP, Shao XQ, Li DF, Yu HD, Han MY, Adv. Mater., 17(1), 42 (2005)
  45. Wei XZ, Wang HJ, Zhu GF, Chen JY, Zhu LP, Ceram. Int., 39, 4009 (2013)