화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Polymer(Korea), Vol.41, No.6, 915-925, November, 2017
DOI10.7317/pk.2017.41.6.915  Export Citation
성장핵을 사용한 유화중합을 통한 Poly(styrene-co-acrylic acid)/Polystyrene 비등방성 나노입자의 제조
Fabrication of Poly(styrene-co-acrylic acid)/Polystyrene Anisotropic Nanoparticles via Seeded Emulsion Polymerization
Feng Zhou, Shaohui Lin, Garry L. Rempel1, and Qinmin Pan†
  • Green Polymer and Catalysis Technology Laboratory, College of Chemistry, Chemical Engineering and Material Science, Soochow University, Suzhou 215123, Jiangsu Province, People’s Republic of China
  • 1Department of Chemical Engineering, University of Waterloo, Waterloo, Ontario, N2L 3G1, Canada
E-mail:
Anisotropic nanoparticles have potentially various important applications, especially in 3D printing materials, binders and phase compatible agents, for which it is essential that the components and the structures are well designed and controlled. This paper investigated nanoparticles consisting of two lobes with opposite properties. As a model system, synthesis of poly(styrene-co-acrylic acid)/polystyrene anisotropic nanoparticles was studied and the effects of temperature, surfactant amount, inhibitors, and initiators for the involved polymerization procedures, and the swelling temperature, and swelling ratio for making the second lobe, on the morphology and size of the produced particles , were investigated. As a result, the anisotropic nanoparticles with uniform asymmetry, one lobe with hydrophilicity and the other with hydrophobicity, were successfully realized. The apparent size of the nanoparticles was below 200 nm, and the strategies for achieving various morphologies, such as snowman-like, potato-like and dumbbell-like, were established. The anisotropic nanoparticles achieved in this study are very useful in the 3D material development that is involved in our another research.
Keywords:snowman-like;anisotropic nanoparticles;3D printing materials;hydrophilicity;hydrophobicity
  1. De Gennes PG, Rev. Mod Phys., 64, 4 (1992)
  2. Chen YH, Wang CY, Li Y, Tong Z, Prog. Chem., 21, 7 (2009)
  3. Lee J, Yezer BA, Prieve DC, Behrens SH, Langmuir, 32(13), 3095 (2016)
  4. Liu B, Liu JG, Liang FX, Wang Q, Zhang CL, Qu XZ, Li JL, Qiu D, Yang ZZ, Macromolecules, 45(12), 5176 (2012)
  5. Okubo M, Fujibayashi T, Yamada M, Minami H, Colloid Polym. Sci., 283, 1041 (2005)
  6. Hoffmann M, Lu Y, Schrinner M, Ballauff M, J. Phys. Chem. B, 112, 8 (2008)
  7. Huang HF, Liu HR, J. Polym. Sci. A: Polym. Chem., 48(22), 5198 (2010)
  8. Tang C, Zhang CL, Liu JG, Qu XZ, Li JL, Yang ZZ, Macromolecules, 43(11), 5114 (2010)
  9. Kegel WK, Breed D, Elsesser M, Pine DJ, Langmuir, 22, 2 (2006)
  10. Liu YD, Fang FF, Choi HJ, Langmuir, 26, 6 (2010)
  11. Wang FW, Liu HR, Zhang JD, Zhou XT, Zhang XY, J. Polym. Sci. A: Polym. Chem., 50(22), 4599 (2012)
  12. Liu X, Pan MW, Yuan JF, Niu Q, Wang XM, Zhang KC, Rsc. Adv., 4, 4163 (2014)
  13. Niu Q, Pan MW, Yuan JF, Liu X, Wang XM, Yu HF, Macromol. Rapid Commun., 34(17), 1363 (2013)
  14. Glaser N, Adams DJ, Boker A, Krausch G, Langmuir, 22, 3 (2006)
  15. Walther A, Hoffmann M, Muller AHE, Angew. Chem., 120, 723 (2008)
  16. Nie HR, Zhang C, Liu YW, He AH, Macromolecules, 49(6), 2238 (2016)
  17. Zhao LL, Zhu LJ, Chen Y, Wang Q, Li JL, Zhang CL, Liang FX, Qu XZ, Yang ZZ, Chem. Commun., 49, 6161 (2013)
  18. Kirillova A, Schliebe C, Stoychev G, Jakob A, Lang H, Synytska A, ACS Appl. Mater. Interfaces, 7, 21218 (2015)
  19. Zentgraf T, Valentine J, Tapia N, Li JS, Zhang XA, Adv. Mater., 22(23), 2561 (2010)
  20. Li D, He YJ, Wang S, J. Phys. Chem., 113, 3 (2009)
  21. Tanaka T, Okayama M, Minami H, Okubo M, Langmuir, 26, 5 (2010)
  22. Walther A, Andre X, Drechsler M, Abetz V, Muller AHE, J. Am. Chem. Soc., 129, 12 (2007)
  23. Erhardt R, Boker A, Zettl H, Kaya H, Hintzen WP, Krausch G, Abetz V, Mueller AHE, Macromolecules, 34, 7 (2001)
  24. Kraft DJ, Vlug WS, Kats CMV, Blaaderen AV, Imhof A, Kegel WK, J. Am. Chem. Soc., 131, 5 (2009)
  25. Li ZF, Lee D, Rubner MF, Cohen RE, Macromolecules, 38, 4 (2005)
  26. Cayre O, Paunov VN, Velev OD, Chem. Commun., 18, 2296 (2003)
  27. Kim JW, Larsen RJ, Weitz DA, J. Am. Chem. Soc., 128, 4 (2006)
  28. Mock EB, Zukoski CF, Langmuir, 26(17), 13747 (2010)
  29. Park JG, Forster JD, Dufresne ER, J. Am. Chem. Soc., 132, 2 (2010)
  30. Saito N, Kagari Y, Okubo M, Langmuir, 22, 6 (2006)
  31. Saito N, Nakatsuru R, Kagari Y, Okubo M, Langmuir, 23, 7 (2007)
  32. Saito N, Kagari Y, Okubo M, Langmuir, 23, 6 (2007)
  33. Higuchi T, Tajima A, Yabu H, Shimomura M, Soft Matter, 4, 1302 (2008)
  34. Kim JW, Lee D, Shum HC, Weitz DA, Adv. Mater., 20(17), 3239 (2008)
  35. Fujibayashi T, Okubo M, Langmuir, 23, 5 (2007)
  36. Okubo M, Makromal. Chem., Macromol. Symp., 35/36, 16 (1990).
  37. Durant YG, Carrier R, Sundberg DC, Polym. React. Eng., 11(3), 433 (2003)
  38. Sheu HR, Elaasser MS, Vanderhoff JW, J. Polym. Sci. A: Polym. Chem., 28, 22 (1990)
  39. Mock EB, De Bruyn H, Hawkett BS, Gilbert RG, Zukoski CF, Langmuir, 22(9), 4037 (2006)
  40. Cho I, Lee KW, J. Appl. Polym. Sci., 30, 24 (1985)
  41. Skjeltorp AT, Ugelstad J, Ellingsen T, J. Colloid Interface Sci., 113, 6 (1986)
  42. Pan MW, Yang LY, Guan B, Lu MS, Zhong GJ, Zhu L, Soft Matter, 7, 11187 (2011)
  43. Shao Q, Wang CG, Zheng H, Wang JM, Polym. Bull., 10, 5 (2007)
  44. Yuan JF, Wang LX, Zhu L, Pan MW, Wang WJ, Liu Y, Liu G, Langmuir, 31(14), 4087 (2015)