In2O3 nanocrystal.p conjugated molecule hybrid materials for high-capacity anode in lithium ion battery

Hien Thu Pham; Don-Sung Lee; Tung Duy Dao; Hyun-Dam Jeong

Journal of Industrial and Engineering Chemistry, Vol.57, 22-27, January, 2018

DOI10.1016/j.jiec.2017.08.003 Export Citation

In2O3 nanocrystal.p conjugated molecule hybrid materials for high-capacity anode in lithium ion battery

Hien Thu Pham, Don-Sung Lee, Tung Duy Dao, and Hyun-Dam Jeong^†

Department of Chemistry, Chonnam National University, Gwangju 500-757, Republic of Korea

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Novel approach to fabricate In2O3 nanocrystal (NC)-π conjugated molecule 4,4'-ethyne-1,2-diyldiben- zoic acid (EBA) hybrid materials by ligand exchange process, Sonogashira coupling reaction, and their utility as a lithium ion battery anode material have been developed. Here, discharge capacity of 900 mAh g-1, excellent rate performance under ultrahigh current density of 20 C, and initial Coulombic efficiency of 60% at moderate charging/discharging current density of 5 C after 100 cycles have been demonstrated, which are synergistically capable of overcoming the drawback of previous In2O3 material. The π-π network allows fast electron/Li+ transport and significant decrease in interfacial resistance in charge/discharge state.

Keywords:In2O3;Nanocrystal;p conjugated molecule;Hybrid material;Li-ion battery

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[4] Park CM, Kim JH, Kim H, Sohn HJ, Chem. Soc. Rev., 39, 3115 (2010)

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[7] Reddy MV, Rao GVS, Chowdari BVR, Chem. Rev., 113(7), 5364 (2013)

[8] Li H, Huang XJ, Chen LQ, Solid State Ion., 123(1-4), 189 (1999)

[9] Liang C, Gao M, Pan H, Liu Y, Yan M, J. Alloy. Compd., 575, 246 (2013)

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[11] Ma J, Lian J, Duan X, Liu X, Zheng W, J. Phys. Chem., 114, 10671 (2010)

[12] Kwak BS, Jo SW, Park KS, Cho TW, Jeon J, Chung KI, Kang M, J. Ind. Eng. Chem., 46, 111 (2017)

[13] Zhang Q, Uchaker E, Candelaria SL, Cao G, Chem. Soc. Rev., 42, 3127 (2013)

[14] Yin YX, Xin S, Guo YG, Part. Part. Syst. Charact., 30(9), 737 (2013)

[15] Oszajca MF, Bodnarchuk MI, Kovalenko MV, Chem. Mater., 26, 5422 (2014)

[16] Wang HL, Cui LF, Yang YA, Casalongue HS, Robinson JT, Liang YY, Cui Y, Dai HJ, J. Am. Chem. Soc., 132(40), 13978 (2010)

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[19] Lou XW, Deng D, Lee JY, Feng J, Archer LA, Adv. Mater., 20(2), 258 (2008)

[20] Chan CK, Peng HL, Liu G, McIlwrath K, Zhang XF, Huggins RA, Cui Y, Nat. Nanotechnol., 3(1), 31 (2008)

[21] Zhou YN, Zhang H, Xue MZ, Wu CL, Wu XJ, Fu ZW, J. Power Sources, 162(2), 1373 (2006)

[22] Ho WH, Li CF, Liu HC, Yen SK, J. Power Sources, 175(2), 897 (2008)

[23] Wang B, Luo B, Li X, Zhi L, Mater. Today, 15, 544 (2012)

[24] Zhang Y, Jiang C, Zhuang S, Lu M, Cai Y, RCS Adv., 6, 49782 (2016)

[25] Seo SD, Lee GH, Lim AH, Min KM, Kim JC, Shim HW, Park KS, Kim DW, RCS Adv., 2, 3315 (2012)

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[29] Lee DW, Yoo BR, J. Ind. Eng. Chem., 28, 1 (2016)

[30] Bae JW, Park JY, Kwon OS, Lee CS, J. Ind. Eng. Chem., 51, 1 (2017)

[31] Pham HT, Jeong HD, Bull. Korean Chem. Soc., 35, 2505 (2014)

[32] Pham HT, Jeong HD, ACS Appl. Mater. Interfaces, 7, 11660 (2015)

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