Characterization and controlling thermal expansion of materials with kosnarite- and langbeinite-type structures

Vladimir I. Pet’kov; Alexander S. Shipilov; Anton S. Dmitrienko; Artemy A. Alekseev

Journal of Industrial and Engineering Chemistry, Vol.57, 236-243, January, 2018

DOI10.1016/j.jiec.2017.08.029 Export Citation

Characterization and controlling thermal expansion of materials with kosnarite- and langbeinite-type structures

Vladimir I. Pet’kov^†, Alexander S. Shipilov, Anton S. Dmitrienko, and Artemy A. Alekseev

Lobachevsky State University of Nizhni Novgorod, Gagarin Av., 23, 603950 Nizhni Novgorod, Russia, Russian Federation

E-mail:

MZr2(TO4)x(PO4)3-x (M = Li, Na, K, Rb, Cs; T = As, V) solid solutions, NaFeZr(PO4)2SO4 and Pb2/3FeZr(PO4)7/ 3(SO4)2/3 with mineral kosnarite structure and KPbMgTi(PO4)3, K5/3MgE4/3(PO4)3 (E = Ti, Zr) with mineral langbeinite structure have been synthesized. According to the yielded results, which encompass thermal expansion data and crystallographic information about the structure of individual compounds and solid solutions, the meaningful selection of compounds with kosnarite and langbeinite structure for novel materials with controllable thermal expansion was carried out. The potassium-, rubidium-, and cesiumcontaining arsenates, arsenate.phosphates, vanadate.phosphates and Pb2/3FeZr(PO4)7/3(SO4)2/3 are low expansion materials (αav < 2 x 10-6 K-1); sodium.zirconium arsenate and sodium.zirconium and lithium.zirconium arsenate.phosphates, vanadate.phosphates and K5/3MgZr4/3(PO4)3 have intermediate thermal expansion (3 x 10-6 K-1< αav< 7 x 10-6 K-1); and lithium.zirconium arsenate, KPbMgTi (PO4)3, K5/3MgTi4/3(PO4)3 are the high expansion material (αav> 7 x 10-6 K-1). The present results demonstrate that change of the size of alkali metal cation, anion substitution and varying of solid solution composition can produce kosnarite ceramics with controlled linear thermal expansion coefficients and extremely low thermal expansion anisotropy or langbeinite ceramics with isotropic expansion.

Keywords:Thermal expansion;X-ray difractometry;Ceramics;NZP family;Langbeinite-type family

[References]

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Pet’kov VI, Russ. Chem. Rev., 81, 606 (2012)
Kamali K, Ravindran TR, Shekar NVC, Pandey KK, Sharma SM, J. Solid State Chem., 221, 285 (2015)
Pet’kov V, Asabina E, Loshkarev V, Sukhanov M, J. Nucl. Mater., 471, 122 (2016)
Pet’kov VI, Asabina EA, Glass Ceram., 61, 233 (2004)
Pet’kov VI, Dmitrienko AS, Sukhanov MV, Kovalskii AM, J. Therm. Anal. Calorim., 127, 2093 (2017)
Samiee M, Radhakrishnan B, Rice Z, Deng Z, Meng YS, Ong SP, Luo J, J. Power Sources, 347, 229 (2017)
ceramics NZP, Am. Ceram. Soc. Bull., 76, 71 (1997)
Kim KW, Yang SH, Kim MY, Lee MS, Lim J, Chang DR, Kim HS, J. Ind. Eng. Chem., 36, 279 (2016)
Bohre A, Avasthi K, Pet'kov VI, J. Ind. Eng. Chem., 50, 1 (2017)
Pet’kov VI, Orlova AI, Inorg. Mater., 39, 1013 (2003)
Lenain GE, McKinstry HA, Alamo J, Agraval DK, J. Mater. Sci., 22, 17 (1987)
Pet’kov VI, Orlova AI, Kasantsev GN, Samoilov SG, Spiridonova ML, J. Therm. Anal. Calorim., 66, 623 (2001)
Oikonomou P, Dedeloudis C, Stournaras CJ, Ftikos C, J. Eur. Ceram. Soc., 27, 1253 (2007)
Asabina E, Pet’kov V, Mayorov P, Lavrenov D, Schelokov I, Kovalsky A, Pure Appl. Chem., 89, 523 (2017)
Alamo J, Solid State Ion., 63-65, 547 (1993)
Lightfoot P, Woodcock DA, Jorgensen JD, Short S, J. Inorg. Mater., 1, 53 (1999)
Catti M, Comotti A, Di Blas S, Chem. Mater., 15, 1628 (2003)
Pet’kov VI, Asabina EA, Shchelokov IA, Inorg. Mater., 49, 502 (2013)
Pet’kov VI, Shipilov AS, Sukhanov MV, Inorg. Mater., 51, 1079 (2015)
Limaye SY, Agraval DK, McKinstry HA, J. Am. Ceram. Soc., 70, 232 (1987)
Zhang B, Guo J, J. Eur. Ceram. Soc., 15, 929 (1995)
Liu XS, Li F, Song WB, Yuan BH, Cheng YG, Liang EJ, Chao MJ, Ceram. Int., 40, 6013 (2014)
Pet’kov VI, Asabina EA, Markin AV, Alekseev AA, Smirnova NN, J. Therm. Anal. Calorim., 124, 1535 (2016)
Martynov KV, Nekrasov AN, Kotel’nikov AR, Tananaev IG, Glass Phys. Chem., 43, 75 (2017)
James JD, Spittle JA, Brown SGR, Evans RW, Meas. Sci. Technol., 12, R1 (2001)
Brochu R, Elyacoubi M, Louer M, Serghini A, Alami M, Louer D, Mater. Res. Bull., 32(1), 15 (1997)
Pet’kov VI, Asabina EA, Indian J. Chem., 52A, 350 (2013)
Pet’kov VI, Sukhanov MV, Shipilov AS, Kurazhkovskaya VS, Borovikova EY, Pinus Y, Yaroslavtsev AB, Inorg. Mater., 50, 263 (2014)
Sukhanov MV, Pet’kov VI, Firsov DV, Kurazhkovskaya VS, Borovikova EY, Russ. J. Inorg. Chem., 56, 1351 (2011)
Pet’kov VI, Shipilov AS, Sukhanov MV, Kurazhkovskaya VS, Borovikova EY, Russ. J. Inorg. Chem., 59, 1201 (2014)
Pet’kov VI, Sukhanov MV, Shipilov AS, Kurazhkovskaya VS, Borovikova EY, Sakharov NV, Ermilova MM, Orekhova NV, Russ. J. Inorg. Chem., 58, 1015 (2013)
Pet’kov VI, Alekseev AA, Asabina EA, Borovikova EY, Kovalskii AM, Russ. J. Inorg. Chem., 62, 870 (2017)

[Referenced By]

[1] Anantharamulu N, Rao KK, Rambabu G, Kumar BV, Radha V, Vithal M, J. Mater. Sci., 46(9), 2821 (2011)

[2] Pet’kov VI, Russ. Chem. Rev., 81, 606 (2012)

[3] Kamali K, Ravindran TR, Shekar NVC, Pandey KK, Sharma SM, J. Solid State Chem., 221, 285 (2015)

[4] Pet’kov V, Asabina E, Loshkarev V, Sukhanov M, J. Nucl. Mater., 471, 122 (2016)

[5] Pet’kov VI, Asabina EA, Glass Ceram., 61, 233 (2004)

[6] Pet’kov VI, Dmitrienko AS, Sukhanov MV, Kovalskii AM, J. Therm. Anal. Calorim., 127, 2093 (2017)

[7] Samiee M, Radhakrishnan B, Rice Z, Deng Z, Meng YS, Ong SP, Luo J, J. Power Sources, 347, 229 (2017)

[8] ceramics NZP, Am. Ceram. Soc. Bull., 76, 71 (1997)

[9] Kim KW, Yang SH, Kim MY, Lee MS, Lim J, Chang DR, Kim HS, J. Ind. Eng. Chem., 36, 279 (2016)

[10] Bohre A, Avasthi K, Pet'kov VI, J. Ind. Eng. Chem., 50, 1 (2017)

[11] Pet’kov VI, Orlova AI, Inorg. Mater., 39, 1013 (2003)

[12] Lenain GE, McKinstry HA, Alamo J, Agraval DK, J. Mater. Sci., 22, 17 (1987)

[13] Pet’kov VI, Orlova AI, Kasantsev GN, Samoilov SG, Spiridonova ML, J. Therm. Anal. Calorim., 66, 623 (2001)

[14] Oikonomou P, Dedeloudis C, Stournaras CJ, Ftikos C, J. Eur. Ceram. Soc., 27, 1253 (2007)

[15] Asabina E, Pet’kov V, Mayorov P, Lavrenov D, Schelokov I, Kovalsky A, Pure Appl. Chem., 89, 523 (2017)

[16] Alamo J, Solid State Ion., 63-65, 547 (1993)

[17] Lightfoot P, Woodcock DA, Jorgensen JD, Short S, J. Inorg. Mater., 1, 53 (1999)

[18] Catti M, Comotti A, Di Blas S, Chem. Mater., 15, 1628 (2003)

[19] Pet’kov VI, Asabina EA, Shchelokov IA, Inorg. Mater., 49, 502 (2013)

[20] Pet’kov VI, Shipilov AS, Sukhanov MV, Inorg. Mater., 51, 1079 (2015)

[21] Limaye SY, Agraval DK, McKinstry HA, J. Am. Ceram. Soc., 70, 232 (1987)

[22] Zhang B, Guo J, J. Eur. Ceram. Soc., 15, 929 (1995)

[23] Liu XS, Li F, Song WB, Yuan BH, Cheng YG, Liang EJ, Chao MJ, Ceram. Int., 40, 6013 (2014)

[24] Pet’kov VI, Asabina EA, Markin AV, Alekseev AA, Smirnova NN, J. Therm. Anal. Calorim., 124, 1535 (2016)

[25] Martynov KV, Nekrasov AN, Kotel’nikov AR, Tananaev IG, Glass Phys. Chem., 43, 75 (2017)

[26] James JD, Spittle JA, Brown SGR, Evans RW, Meas. Sci. Technol., 12, R1 (2001)

[27] Brochu R, Elyacoubi M, Louer M, Serghini A, Alami M, Louer D, Mater. Res. Bull., 32(1), 15 (1997)

[28] Pet’kov VI, Asabina EA, Indian J. Chem., 52A, 350 (2013)

[29] Pet’kov VI, Sukhanov MV, Shipilov AS, Kurazhkovskaya VS, Borovikova EY, Pinus Y, Yaroslavtsev AB, Inorg. Mater., 50, 263 (2014)

[30] Sukhanov MV, Pet’kov VI, Firsov DV, Kurazhkovskaya VS, Borovikova EY, Russ. J. Inorg. Chem., 56, 1351 (2011)

[31] Pet’kov VI, Shipilov AS, Sukhanov MV, Kurazhkovskaya VS, Borovikova EY, Russ. J. Inorg. Chem., 59, 1201 (2014)

[32] Pet’kov VI, Sukhanov MV, Shipilov AS, Kurazhkovskaya VS, Borovikova EY, Sakharov NV, Ermilova MM, Orekhova NV, Russ. J. Inorg. Chem., 58, 1015 (2013)

[33] Pet’kov VI, Alekseev AA, Asabina EA, Borovikova EY, Kovalskii AM, Russ. J. Inorg. Chem., 62, 870 (2017)