Self-Cleaning and Photocatalytic Performance of TiO2 Coating Films Prepared by Peroxo Titanic Acid

Hemraj M. Yadav; Jung-Sik Kim

Korean Journal of Materials Research, Vol.27, No.11, 577-582, November, 2017

DOI10.3740/MRSK.2017.27.11.577 Export Citation

Self-Cleaning and Photocatalytic Performance of TiO2 Coating Films Prepared by Peroxo Titanic Acid

Hemraj M. Yadav^{1, 2}, and Jung-Sik Kim^{1, †}

¹Department of Materials Science and Engineering, University of Seoul, Seoul 02504, Republic of Korea
²Department of Energy and Materials Engineering, Dongguk University, Seoul 04620, Republic of Korea

E-mail:

Self-cleaning and photocatalytic TiO2 thin films were prepared by a facile sol-gel method followed by spin coating using peroxo titanic acid as a precursor. The as-prepared thin films were heated at low temperature(110 °C) and high temperature (400 °C). Thin films were characterized by X-ray diffraction(XRD), Field-emission scanning electron microscopy(FESEM), UVVisible spectroscopy and water contact angle measurement. XRD analysis confirms the low crystallinity of thin films prepared at low temperature, while crystalline anatase phase was found the for high temperature thin film. The photocatalytic activity of thin films was studied by the photocatalytic degradation of methylene blue dye solution. Self-cleaning and photocatalytic performance of both low and high temperature thin films were compared.

Keywords:TiO2;thin films;sol-gel;self-cleaning;photocatalysis;methylene blue.

[References]

Nagaveni K, Hegde MS, Ravishankar N, Subbanna GN, Madrao G, Langmuir, 20(7), 2900 (2004)
Nakata K, Fujishima A, J. Photochem. Photobiol. C Photochem. Rev., 13, 169 (2012)
Linsebigler AL, Lu GQ, Yates JT, Chem. Rev., 95(3), 735 (1995)
Yadav HM, Kolekar TV, Barge AS, Thorat ND, Delekar SD, Kim BM, Kim BJ, Kim JS, J. Mater. Sci. Mater. Electron., 27, 526 (2016)
Yadav HM, Kolekar TV, Pawar SH, Kim JS, J. Mater. Sci. -Mater. Med., 27, 57 (2016)
Medina-Valtierra J, Frausto-Reyes C, Ramirez-Ortiz J, Camarillo-Martinez G, Ind. Eng. Chem. Res., 48(2), 598 (2009)
Kim BM, Kim JS, Korean J. Mater. Res., 26(2), 73 (2016)
Oshani F, Marandi R, Rasouli S, Farhoud MK, Appl. Surf. Sci., 311, 308 (2014)
Sotelo-Vazquez C, Quesada-Cabrera R, Darr JA, Parkin IP, J. Mater. Chem., 2, 7082 (2014)
Wang ZC, Hu XF, Thin Solid Films, 352(1-2), 62 (1999)
Yadav HM, Kim JS, J. Mater. Sci. Mater. Electron., 27, 10082 (2016)
Mills A, Elliott N, Parkin IP, O’Neill SA, Clark RJ, J. Photochem. Photobiol. A-Chem., 151, 171 (2002)
Mali SS, Betty CA, Bhosale PN. Patil PS, CrystEngComm., 13, 6349 (2011)
Heo CH, Lee SB, Boo JH, Thin Solid Films, 475(1-2), 183 (2005)
Ge L, Xu M, J. Sol-Gel Sci. Technol., 43, 1 (2007)
Sonawane RS, Hegde SG, Dongare MK, Mater. Chem. Phys., 77(3), 744 (2003)
Medina-Valtierra J, Garcia-Servin J, Frausto-Reyes C, Calixto S, Appl. Surf. Sci., 252(10), 3600 (2006)
Yuan Z, Li B, Zhang J, Xu C, Ke J, J. Sol-Gel Sci. Technol., 39, 249 (2006)
Kim DK, Maeng WY, Korean J. Mater. Res., 26(5), 271 (2016)
Mennig M, Oliveira PW, Schmidt H, Thin Solid Films, 351(1-2), 99 (1999)
Wang Y, Li B, Liu T, Xu C, Ge Z, Colloids Surf. A: Physicochem. Eng. Asp., 441, 298 (2014)
Zhang X, Fujishima A, Jin M, Emeline AV, Murakami T, J. Phys. Chem. B, 110, 25142 (2006)
Fujishima A, Rao TN, Tryk DA, J. Photochem. Photobiol. C, 1, 1 (2000)
Lazar M, Varghese S, Nair S, Catalysts, 2, 572 (2012)
Hashimoto K, Irie H, Fujishima A, Jpn. J. Appl. Phys., 44, 8269 (2005)
Fujishima A, Zhang X, Tryk D, Surf. Sci. Rep., 63, 515 (2008)

[1] Nagaveni K, Hegde MS, Ravishankar N, Subbanna GN, Madrao G, Langmuir, 20(7), 2900 (2004)

[2] Nakata K, Fujishima A, J. Photochem. Photobiol. C Photochem. Rev., 13, 169 (2012)

[3] Linsebigler AL, Lu GQ, Yates JT, Chem. Rev., 95(3), 735 (1995)

[4] Yadav HM, Kolekar TV, Barge AS, Thorat ND, Delekar SD, Kim BM, Kim BJ, Kim JS, J. Mater. Sci. Mater. Electron., 27, 526 (2016)

[5] Yadav HM, Kolekar TV, Pawar SH, Kim JS, J. Mater. Sci. -Mater. Med., 27, 57 (2016)

[6] Medina-Valtierra J, Frausto-Reyes C, Ramirez-Ortiz J, Camarillo-Martinez G, Ind. Eng. Chem. Res., 48(2), 598 (2009)

[7] Kim BM, Kim JS, Korean J. Mater. Res., 26(2), 73 (2016)

[8] Oshani F, Marandi R, Rasouli S, Farhoud MK, Appl. Surf. Sci., 311, 308 (2014)

[9] Sotelo-Vazquez C, Quesada-Cabrera R, Darr JA, Parkin IP, J. Mater. Chem., 2, 7082 (2014)

[10] Wang ZC, Hu XF, Thin Solid Films, 352(1-2), 62 (1999)

[11] Yadav HM, Kim JS, J. Mater. Sci. Mater. Electron., 27, 10082 (2016)

[12] Mills A, Elliott N, Parkin IP, O’Neill SA, Clark RJ, J. Photochem. Photobiol. A-Chem., 151, 171 (2002)

[13] Mali SS, Betty CA, Bhosale PN. Patil PS, CrystEngComm., 13, 6349 (2011)

[14] Heo CH, Lee SB, Boo JH, Thin Solid Films, 475(1-2), 183 (2005)

[15] Ge L, Xu M, J. Sol-Gel Sci. Technol., 43, 1 (2007)

[16] Sonawane RS, Hegde SG, Dongare MK, Mater. Chem. Phys., 77(3), 744 (2003)

[17] Medina-Valtierra J, Garcia-Servin J, Frausto-Reyes C, Calixto S, Appl. Surf. Sci., 252(10), 3600 (2006)

[18] Yuan Z, Li B, Zhang J, Xu C, Ke J, J. Sol-Gel Sci. Technol., 39, 249 (2006)

[19] Kim DK, Maeng WY, Korean J. Mater. Res., 26(5), 271 (2016)

[20] Mennig M, Oliveira PW, Schmidt H, Thin Solid Films, 351(1-2), 99 (1999)

[21] Wang Y, Li B, Liu T, Xu C, Ge Z, Colloids Surf. A: Physicochem. Eng. Asp., 441, 298 (2014)

[22] Zhang X, Fujishima A, Jin M, Emeline AV, Murakami T, J. Phys. Chem. B, 110, 25142 (2006)

[23] Fujishima A, Rao TN, Tryk DA, J. Photochem. Photobiol. C, 1, 1 (2000)

[24] Lazar M, Varghese S, Nair S, Catalysts, 2, 572 (2012)

[25] Hashimoto K, Irie H, Fujishima A, Jpn. J. Appl. Phys., 44, 8269 (2005)

[26] Fujishima A, Zhang X, Tryk D, Surf. Sci. Rep., 63, 515 (2008)