Manganese oxide with different composition and morphology as electrocatalyst for oxygen evolution reaction

Hwansu Sim; Jooyoung Lee; Taekyung Yu; Byungkwon Lim

Korean Journal of Chemical Engineering, Vol.35, No.1, 257-262, January, 2018

DOI10.1007/s11814-017-0247-2 Export Citation

Manganese oxide with different composition and morphology as electrocatalyst for oxygen evolution reaction

Hwansu Sim, Jooyoung Lee, Taekyung Yu^{1, †}, and Byungkwon Lim^†

School of Advanced Materials Science and Engineering, Sungkyunkwan University (SKKU), Suwon 16419, Korea
¹Department of Chemical Engineering, Kyung Hee University, Yongin 17104, Korea

E-mail:,

Electrochemical activity and stability depend on the composition and morphology of nanocrystals. Mn3O4 nanoplates, Mn2O3 nanoplates, and porous Mn2O3 nanoplates were synthesized by heat treatment of Mn-glycolate nanoplates prepared by the wet-chemical method. In this research, the morphology and composition of the nanoplates could be easily controlled by varying the annealing temperature. The synthesized porous Mn2O3 nanoplates exhibited better electrocatalytic activities compared with Mn3O4 and Mn2O3 nanoplates, as similar as commercial IrO2 catalyst.

Keywords:Manganese Oxides;Composition;Porous Structure;Oxygen Evolution Reaction;Stability

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[4] Dau H, Zaharieva I, Acc. Chem. Res., 42, 1861 (2009)

[5] Duan L, Tong L, Xu Y, Sun L, Energy Environ. Sci., 4, 3296 (2011)

[6] Cao R, Lai W, Du P, Energy Environ. Sci., 5, 8134 (2012)

[7] Reier T, Oezaslan M, Strasser P, ACS Catal., 2, 1765 (2012)

[8] Li Y, Wang H, Xie L, Liang Y, Hong G, Dai H, J. Am. Ceram. Soc., 133, 7296 (2011)

[9] Casalongue HGS, Ng ML, Kaya S, Friebel D, Ogasawara H, Nilsson A, Angew. Chem.-Int. Edit., 53, 7169 (2014)

[10] Nakagawa T, Bjorge NS, Murray RW, J. Am. Chem. Soc., 131(43), 15578 (2009)

[11] Nakagawa T, Beasley CA, Murray RW, J. Phys. Chem., 113, 12958 (2009)

[12] Lee Y, Suntivich J, May KJ, Perry EE, Shao-Horn Y, J. Phys. Chem. Lett., 3, 399 (2012)

[13] Suntivich J, May KJ, Gasteiger HA, Goodenough JB, Shao-Horn Y, Science, 334(6061), 1383 (2011)

[14] Louie MW, Bell AT, J. Am. Chem. Soc., 135(33), 12329 (2013)

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[16] Burke MS, Kast MG, Trotochaud L, Smith AM, Boettcher SW, J. Am. Chem. Soc., 137(10), 3638 (2015)

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[18] Xiao W, Wang D, Lou XW, J. Phys. Chem., 114, 1694 (2010)

[19] Gorlin Y, Chung CJ, Nordlund D, Clemens BM, Jaramillo TF, ACS Catal., 2, 2687 (2012)

[20] Jiao F, Frei H, Chem. Commun., 46, 2920 (2010)

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[22] Xu Y, Jiang H, Li X, Xiao H, Xiao W, Wu T, J. Mater. Chem., 2, 13345 (2014)

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[25] Koenigsmann C, Semple DB, Sutter E, Tobierre SE, Wong SS, ACS Appl. Mater. Interfaces, 5, 5518 (2013)

[26] Yan Y, Xia B, Ge X, Liu Z, Wang JY, Wang X, ACS Appl. Mater. Interfaces, 5, 12794 (2013)

[27] Zhang H, Ma Z, Duan J, Liu H, Liu G, Wang T, Chang K, Li M, Shi L, Meng X, Wu K, Ye J, ACS Nano, 10, 684 (2016)

[28] Liu L, Yang Z, Liang H, Yang H, Yang Y, Mater. Lett., 61, 891 (2010)

[29] Sun Y, Hu X, Luo W, Huang Y, J. Mater. Chem., 22, 19190 (2012)

[30] Zhang Y, Yan Y, Wang X, Li G, Deng D, Jiang L, Shu C, Wang C, Chem. Eur. J., 20, 6126 (2014)

[31] Huang SZ, Cai Y, Jin J, Liu J, Li Y, Yu Y, Wang HE, Chen LH, Su BL, Nano Energy, 12, 833 (2015)

[32] Ramesh K, Chen LW, Chen FX, Liu Y, Wang Z, Han YF, Catal. Today, 131(1-4), 477 (2008)

[33] Liu B, Hu X, Xu H, Luo W, Sun Y, Huang Y, Sci. Rep., 4, 4229 (2014)

[34] Petkovich ND, Stein A, Chem. Soc. Rev., 42, 3721 (2013)

[35] Yang XY, Chen LH, Li Y, Rooke JC, Sanchez C, Su BL, Chem. Soc. Rev., 46, 481 (2017)

[36] Fang YC, Huang YD, Zhang S, Jia W, Wang XC, Guo Y, Jia DZ, Wang LS, Chem. Eng. J., 315, 583 (2017)

[37] Ramirez A, Hillebrand P, Stellmach D, May MM, Bogdanoff P, Fiechter S, J. Phys. Chem., 118, 14073 (2014)

[38] Dubal DP, Dhawale DS, Salunkhe RR, Fulari VJ, Lokhande CD, J. Alloy. Compd., 497, 166 (2010)

[39] Liu G, Gao X, Wang K, He D, Li J, Nano Res., 10, 2096 (2017)