화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.35, No.2, 409-420, February, 2018
DOI10.1007/s11814-017-0307-7  Export Citation
Process optimization for selective hydrogenation of α-pinene over Ni/AlPO4
Chen Yang, Lihong Jiang, Huaibo Wang, Yane Zheng, and Yaming Wang†
  • Faculty of Chemical Engineering, Kunming University of Science and Technology, Kunming 650500, P. R. China
E-mail:
A new supported Ni/AlPO4 catalyst was synthesized and studied for the selective hydrogenation of α- pinene to prepare cis-pinane. The support was flaky morphology with orthorhombic phase and Ni was well dispersed. The surface area of the catalyst was 37.62m2·g -1 with a pore size of 2.83 nm. For the hydrogenation reaction, the performance of the catalyst was positively correlated with the surface area of support and loading content of Ni. Effects of hydrogenation condition were determined and the process was optimized by response surface methodology. The result suggested that the conversion was positively correlated to hydrogenation temperature, duration and catalyst dosage, while the selectivity showed a negative correlation to temperature and catalyst dosage. After optimization, 95.1% of selectivity was obtained under 94.8% of conversion at 405 K, 81 min and 2.28 wt% of catalyst.
Keywords:Aluminophosphate;Nickel;Selective Hydrogenation;α-Pinene;cis-Pinane;Response Surface Methodology
  1. Semikolenov VA, Ilyna II, Simakova IL, Appl. Catal. A: Gen., 211(1), 91 (2001)
  2. Wilderman PR, Shah MB, Jang HH, Stout CD, Halpert JR, J. Am. Chem. Soc., 135(28), 10433 (2013)
  3. Audin E, Turkez H, Geyikoglu F, Biologia, 68, 1004 (2013)
  4. Rezzi S, Bighelli A, Castola V, Casanova J, Ind. Crop. Prod., 21, 71 (2005)
  5. Chouchi D, Gourgouillon D, Courel M, Vital J, da Ponte MN, Ind. Eng. Chem. Res., 40(12), 2551 (2001)
  6. Comelli NA, Ponzi EN, Ponzi MI, Chem. Eng. J., 117(2), 93 (2006)
  7. Sundaravel B, Babu CM, Vinodh R, Cha WS, Jang HT, J. Taiwan. Inst. Chem. Eng., 63, 157 (2016)
  8. Kukhta NA, Vasilenko I, Kostjuk SV, Green Chem., 13, 2362 (2011)
  9. Hou S, Xie C, Yu F, Yuan B, Yu S, RSC Adv., 6, 54806 (2016)
  10. Hou SL, Wang XY, Huang CR, Xie CX, Yu ST, Catal. Lett., 146(3), 580 (2016)
  11. Simakova IL, Solkina Y, Deliy I, Warna J, Murzin DY, Appl. Catal. A: Gen., 356(2), 216 (2009)
  12. Yang X, Liu S, Xie C, Yu S, Liu F, Chin. J. Catal., 32, 643 (2011)
  13. Canova LA, US Patent, 4,018,842 (1977).
  14. Ko SH, Chou TC, Ind. Eng. Chem. Res., 32, 1579 (1993)
  15. Ko SH, Chou TC, Yang TJ, Ind. Eng. Chem. Res., 34(2), 457 (1995)
  16. Zhang JH, Jiang LH, Wu SS, Wang HQ, Wang YM, CIESC J., 67, 2363 (2016)
  17. Ren SB, Qiu JH, Wang CY, Xu BL, Fan YN, Chen Y, Chin. J. Inorg. Chem., 23, 1021 (2007)
  18. Ren SB, Qiu JH, Wang CY, Xu BL, Fan YN, Chen Y, Chin. J. Catal., 28, 651 (2007)
  19. Wang LL, Guo HQ, Chen XP, Huang YY, Ren L, Ding SF, Can. J. Chem. Eng., 93(10), 1770 (2015)
  20. Wang L, Guo H, Chen X, Huang Y, Zhang P, React. Kinet. Mech. Cat., 114, 639 (2015)
  21. Han H, Jiang LH, Wang YM, Huang TY, Wang HQ, Chem. Ind. Fore. Prod., 36, 92 (2016)
  22. Wilson ST, Lok BM, Messina CA, Cannan TR, Flanigen EM, J. Am. Chem. Soc., 104, 1146 (1982)
  23. Wang X, Wang F, Jiang S, Zhong SH, Chin. J. Catal., 32, 352 (2011)
  24. Chakrabortty D, Ganguli J, Satyanarayana C, Microporous Mesoporous Mater., 137, 65 (2011)
  25. Dai WL, Kong WB, Wu GJ, Li N, Li LD, Guan NJ, Catal. Commun., 12, 535 (2011)
  26. Lee YJ, Kim YW, Viswanadham N, Jun KW, Bae JW, Appl. Catal. A: Gen., 374(1-2), 18 (2010)
  27. Bhattacharjee S, Lee YR, Ahn WS, Korean J. Chem. Eng., 34(3), 701 (2017)
  28. Liu Z, Wakihara T, Nishioka D, Oshima K, Takewaki T, Okubo T, Chem. Commun., 50, 2526 (2014)
  29. Li K, Tian Z, Li X, Xu R, Xu Y, Wang L, Ma H, Wang B, Lin L, Angew. Chem.-Int. Edit., 51, 4397 (2012)
  30. Delgado JA, Agueda VI, Uguina MA, Sotelo JL, Fernandez P, Adsorption, 19, 407 (2013)
  31. Song XW, Li Y, Gan L, Wang ZP, Yu JH, Xu RR, Angew. Chem.-Int. Edit., 48, 314 (2009)
  32. Shan X, Maw HP, Lu CW, Microsyst. Technol., 16, 1501 (2010)
  33. Xu W, Huo L, Luo S, Zhang X, Zhao J, Hao Y, Ma Z, Int. J. Microstruc. Mat. Prop., 10, 296 (2015)
  34. Pereira G, Lachenwitzer A, Munoz-Paniagua D, Kasrai M, Norton PR, Abrecht M, Gilbert P, Tribol. Lett., 23, 109 (2006)
  35. Tang K, Yu J, Zhao Y, Liu Y, Wang X, Xu R, J. Mater. Chem., 16, 1741 (2006)
  36. Wang Y, Li Y, Yan Y, Xu J, Guan B, Wang Q, Li J, Yu J, Chem. Commun., 49, 9006 (2013)
  37. Chen JS, Pang WQ, Xu RR, Top. Catal., 9, 93 (1999)
  38. Golubina EV, Lokteva ES, Erokhin AV, Veligzhanin AA, Zubavichus YV, Likholobov VA, Lunin VV, J. Catal., 344, 90 (2016)
  39. Xia JW, He GY, Zhang LL, Sun XQ, Wang X, Appl. Catal. B: Environ., 180, 408 (2016)
  40. Khalfaoui M, Knani S, Hachicha MA, Ben Lamine A, J. Colloid Interface Sci., 263(2), 350 (2003)
  41. Liu YQ, Gao L, J. Am. Ceram. Soc., 86(10), 1651 (2003)
  42. Wright SF, Dollimore D, Dunn JG, Alexander K, Thermochim. Acta, 421(1-2), 25 (2004)
  43. Zhang Y, Chu W, Cao WM, Luo CR, Wen XG, Zhou KL, Plasma Chem. Plasma Process., 20(1), 137 (2000)
  44. Hoffer BW, van Langeveld AD, Janssens JP, Bonne RLC, Lok CM, Moulijn JA, J. Catal., 192(2), 432 (2000)
  45. Salminen E, Maki-Arvela P, Virtanen P, Salmi T, Mikkola JP, Top. Catal., 57, 1533 (2014)
  46. Singh AK, Mukhopadhyay M, Korean J. Chem. Eng., 33(4), 1247 (2016)
  47. Davoodi P, Ghoreishi SM, Hedayati A, Korean J. Chem. Eng., 34(3), 854 (2017)
  48. Cao J, Wu Y, Jin Y, Yilihan P, Huang W, J. Taiwan. Inst. Chem. Eng., 45, 860 (2014)
  49. Ahmed OU, Mjalli FS, Al-Wahaibi T, Al-Wahaibi Y, AlNashef IM, Ind. Eng. Chem. Res., 54(25), 6540 (2015)
  50. Khataee AR, Karimi A, Soltani RDC, Safarpour M, Hanifehpour Y, Joo SW, Appl. Catal. A: Gen., 488, 160 (2014)
  51. Smidt M, Kusic H, Juretic D, Stankov MN, Ukic S, Bolanca T, Rogosic M, Bozic AL, Ind. Eng. Chem. Res., 54(20), 5427 (2015)