화학공학소재연구정보센터
Korean Journal of Chemical Engineering, Vol.35, No.2, 548-556, February, 2018
Enhancement in photocatalytic degradation of methylene blue by LaFeO3-GO integrated photocatalyst-adsorbents under visible light irradiation
E-mail:
Perovskite LaFeO3 photocatalyst prepared by using sol-gel glucose method was assembled on graphene oxide sheets to produce integrated photocatalyst-adsorbents (IPCA) and investigated as photocatalyst for the degradation of methylene blue under visible light irradiation. The prepared photocatalyst was characterized by FTIR, XRD, FESEM, BET specific surface area measurement, TEM/HRTEM and UV-Vis spectroscopy analysis. The FTIR, FESEM and TEM analysis has suggested that the photocatalyst LaFeO3 has been successfully embedded at the surface of the graphene oxide (GO) sheets due to a strong interaction between the photocatalyst and the adsorbents matrix. Methylene blue degradation shows that IPCA possesses higher photodegradation kinetics compared to bare LaFeO3 photocatalyst. The resultant photocatalyst also possesses magnetic properties which can overcome the difficulty in recollecting and removal of photocatalyst suspension in water after photocatalytic treatment.
  1. Ackerman LKG, Lovell MM, Weix DJ, Nature, 524(7566), 454 (2015)
  2. Su F, Lv X, Miao M, Small, 11, 854 (2015)
  3. Yoon JW, Baek MH, Hong JS, Lee CY, Suh JK, Korean J. Chem. Eng., 29(12), 1722 (2012)
  4. Aziz F, Ismail AF, Polym. Bull., 72(7), 1827 (2015)
  5. Yang H, Fu P, Surf. Rev. Lett., 15, 337 (2008)
  6. Peng K, Fu L, Yang H, Ouyang J, Sci. Rep., 6, 19723 (2016)
  7. Yang L, An Y, Dai B, Guo X, Liu Z, Peng B, Korean J. Chem. Eng., 34(2), 476 (2017)
  8. Abdul JM, Vigneswaran S, Shon HK, Nathaporn A, Kandasamy J, Korean J. Chem. Eng., 26(3), 724 (2009)
  9. Chakma S, Praneeth S, Moholkar VS, Ultrason. Sonochem., 38, 652 (2017)
  10. Chakma S, Moholkar VS, J. Taiwan Inst. Chem. Eng., 60, 469 (2016)
  11. Chakma S, Moholkar VS, J. Ind. Eng. Chem., 33, 276 (2016)
  12. Liu LM, Sun KN, Li XK, Zhang M, Liu YB, Zhang NQ, Zhou XL, Int. J. Hydrog. Energy, 37(17), 12574 (2012)
  13. Song P, Wang Q, Zhang Z, Yang Z, Sens. Actuators B-Chem., 147, 248 (2010)
  14. Tang PS, Tong Y, Chen HF, Cao F, Pan GX, Curr. Appl. Phys., 13(2), 340 (2013)
  15. Zhang Q, Huang Y, Peng SQ, Zhang YF, Shen ZX, Cao JJ, Ho WK, Lee SC, Pui DYH, Appl. Catal. B: Environ., 204, 346 (2017)
  16. Zhu J, Li H, Zhong L, Xiao P, Xu X, Yang X, Zhao Z, Li J, ACS Catal., 4, 2917 (2014)
  17. Zhu JJ, Zhao YX, Tang DH, Zhao Z, Carabineiro SAC, J. Catal., 340, 41 (2016)
  18. Mohamed MA, Salleh WNW, Jaafar J, Ismail AF, Nor NAM, Mater. Chem. Phys., 162, 113 (2015)
  19. Yang YC, Lu F, Zhou Z, Song WX, Chen QY, Ji XB, Electrochim. Acta, 113, 9 (2013)
  20. Marcano DC, Kosynkin DV, Berlin JM, Sinitskii A, Sun Z, Slesarev A, Alemany LB, Lu W, Tour JM, ACS Nano, 4, 4806 (2010)
  21. Moon YE, Jung G, Yun J, Kim HI, Mater. Sci. Eng. B-Solid State Mater. Adv. Technol., 178, 1097 (2013)
  22. Liu T, Xu YB, Mater. Chem. Phys., 129(3), 1047 (2011)
  23. Vadivel S, Vanitha M, Muthukrishnaraj A, Balasubramanian N, J. Water Process Eng., 1, 17 (2014)
  24. Lai GS, Lau WJ, Goh PS, Ismail AF, Yusof N, Tan YH, Desalination, 387, 14 (2016)
  25. Thirumalairajan S, Girija K, Ganesh I, Mangalaraj D, Viswanathan C, Balamurugan A, Ponpandian N, Chem. Eng. J., 209, 420 (2012)
  26. Hu R, Li C, Wang X, Sun Y, Jia H, Su H, Zhang Y, Catal. Commun., 29, 35 (2012)
  27. Farhadi S, Momeni Z, Taherimehr M, J. Alloy. Compd., 471, 5 (2009)
  28. Cho YG, Choi KH, Kim YR, Jung JS, Lee SH, Bull. Korean Chem. Soc., 30, 1368 (2009)
  29. Hilder M, Winther-Jensen O, Winther-Jensen B, Mac-Farlane DR, Phys. Chem. Chem. Phys., 14, 14034 (2012)
  30. Yang T, Liu L, Liu J, Chen ML, Wang JH, J. Mater. Chem., 22, 21909 (2012)
  31. Zhu M, Chen P, Liu M, ACS Nano,, 5, 4529 (2011)
  32. Feng J, Liu T, Xu Y, Zhao J, He Y, Ceram. Int., 37, 1203 (2011)
  33. Zhou KW, Wu XH, Wu WW, Xie J, Tang SQ, Liao S, Adv. Powder Technol., 24(1), 359 (2013)
  34. Cen WL, Xiong T, Tang CY, Yuan SD, Dong F, Ind. Eng. Chem. Res., 53(39), 15002 (2014)
  35. Joo JB, Zhang Q, Dahl M, Lee I, Goebl J, Zaera F, Yin Y, Energy Environ. Sci., 5, 6321 (2012)
  36. Ma J, Wu H, Liu Y, He H, J. Phys. Chem., 118, 7434 (2014)
  37. Mohamed MA, Salleh WNW, Jaafar J, Rosmi MS, Hir ZAM, Abd Mutalib M, Ismail AF, Tanemura M, Appl. Surf. Sci., 393, 46 (2017)
  38. Thirumalairajan S, Girija K, Hebalkar NY, Mangalaraj D, Viswanathan C, Ponpandian N, RSC Adv., 3, 7549 (2013)
  39. Zuo R, Du G, Zhang W, Liu L, Liu Y, Mei L, Li Z, Photocatalytic Degradation of Methylene Blue Using TiO2 Impregnated Diatomite, 2014, 1 (2014).
  40. Wang C, Yao J, Int. J. Photoenergy, 2010, 1 (2010)
  41. Wang F, Min S, Han Y, Feng L, Superlattices Microstruct., 48, 170 (2010)
  42. Mohamed MA, Salleh WNW, Jaafar J, Ismail AF, Abd Mutalib M, Sani NAA, Asri SEAM, Ong CS, Chem. Eng. J., 284, 202 (2016)
  43. Li X, Yang H, Appl. Clay Sci., 100, 43 (2014)
  44. Grabowska E, Appl. Catal. B: Environ., 186, 97 (2016)