화학공학소재연구정보센터
Applied Surface Science, Vol.434, 1210-1216, 2018
Structural changes of Ti3SiC2 induced by helium irradiation with different doses
In this study, the microstructure changes of Ti3SiC2 MAX phase material induced by helium irradiation and evolution with a sequence of different helium irradiation doses of 5 x 10(15), 1 x 10(16), 5 x 10(16) and 1 x 10(17) cm(-2) at room temperature (RT) were characterized with grazing incidence X-ray diffraction (GIXRD) and Raman spectra analysis. The irradiation damage process of Ti3SiC2 can be roughly divided into three stages according to the level of helium irradiation dose: (1) for a low damage dose, only crystal and damaged (TiSiC2)-Si-3 exit; (2) at a higher irradiation dose, there is some damaged TiC phase additionally; (3) with a much higher irradiation dose, crystal TiC phase could be found inside the samples as well. Moreover, the 450 degrees C 5 x 10(16) cm(-2) helium irradiation on Ti3SiC2 has confirmed that Ti3SiC2 has much higher irradiation tolerance at higher temperature, which implies that Ti3SiC2 could be a potential future structural and fuel coating material working at high temperature environments. (C) 2017 Elsevier B.V. All rights reserved.