We present a global potential energy surface for the (A) over bar state of NH2 (1(2)A＇) based on application of the reproducing kernel Hilbert space (RMS) interpolation method to high-quality ab initio (multireference configuration-interaction) results. This surface correlates adiabatically to the a(1)Delta state of NH, with a reaction endoergicity of about 8 kcal/mol, but it can also lead to formation of ground-state NH (exoergic by 29 kcal/mol) via nonadiabatic (Renner-Teller) interactions for linear HNH geometries that lie near the bottom of a 94 kcal/mol deep well that is accessible from N(D-2) + H-2 by insertion over a 3.4 kcal/mol barrier. This insertion barrier is about 1 kcal/mol higher in energy than the corresponding insertion barrier associated with the ground state of NH2(1(2)A "). As a result, the A state contributes measurably to both the thermal rate constant for N(D-2) + H-2 and the rate for NH(a(1)Delta) production. Extensive quasiclassical trajectory calculations are performed on the RKHS surface to study the N(2D) + H-2 reaction dynamics, with the nonadiabatic rate constant estimated using a capture model. We find that the cross section for ground-state NH production is comparable to that obtained on the ground-state 1A " surface, except for a 1 kcal/mol shift upward in the effective threshold due to the different barrier height. The cross section for NH(a(1)Delta) production has a higher threshold energy and is about 15% of the ground-state cross section at energies well above threshold.