Utilizing pluronic P123 and MoO42- as morphology directing reagents, the ternary NiFeMoS anemones-like nanorods with scaly surface supported on nickel foam ( NiFeMoS/NF-P) have been synthesized through a twostep method. Firstly, Ni-Fe hydroxides film has been electrodeposited on the surface of NF, leading to a homogeneous doping of NiFe. Then, the anemones-like nanorods with scaly surface have been prepared though a facile hydrothermal sulfuration with co-adding of P123 and MoO42-. SEM and TEM images confirm the NiFeMoS/NF-P has anemones-like nanorods morphology with scale-like surface composed of many nanosheets. With the absence of P123 or MoO42-, scaly surface of NiFeMoS nanorods can't be obtained, implying the role of P123 and MoO(4)(2-)as organic-inorganic hybrids directing reagents. The detailed influence of P123 and MoO42- on NiFeMoS nanostructure and electrocatalytic activity for water splitting has been investigated. NiFeMoS/NF-P as bifunctional electrocatalyst exhibit excellent electrocatalytic performance in 1M KOH, producing a current density of 150 mA cm(-2) at a overpotential of 280 mV for OER and a overpotential of 100 mV at 10 mA cm(-2) for HER. Moreover, in the same system for overall water-splitting, NiFeMoS/NF-P present remarkable performance with a current density of 100 mA cm(-2) at a low cell voltage of 1.52 V.