Inorganic Chemistry, Vol.56, No.21, 13062-13069, 2017
Enhanced similar to 2 mu m Emission of Tm3+ in Lu2O3 by Addition of a Trace Amount of Er3+
Er3+-induced intensity enhancement of similar to 2 mu m emission is observed in 2 atom % Tm3+ doped Lu2O3 under 782 nm excitation. The maximum enhancement reaches 41.9% with only 0.05 atom % Er3+. Er3+ introduces a new quantum cutting process which is proved to be a Tm3+ -> Er3+ -> Tm3+ forward-backward energy transfer (FBET) system. The FBET system is observed to work efficiently even at very low Er3+ concentration. Thus, energy loss due to energy migration among Tm3+ ions is suggested to be suppressed by the FBET process. The Tm3+ -> Er3+ -> Tm3+ FBET system may be a new route to improve the performance of Tm3+ lasers.