화학공학소재연구정보센터
Journal of Chemical and Engineering Data, Vol.62, No.12, 4252-4265, 2017
Densities and Viscosities for Binary Liquid Mixtures of Butan-1-ol + Propane-1,2-diol, + Butane-1,2-diol and 2-Methylpropan-1-ol + Propane-1,2-diol, + Butane-1,2-diol from 298.15 to 333.15 K at 0.1 MPa
This paper presents densities and viscosities of binary mixtures of butan-1-ol (or 2-methylpropan-1-ol) with propane-1,2-diol, and butane-1,2-diol from 298.15 to 333.15 K at 0.1 MPa over the entire concentration range. A vibrating tube densimeter provides the densities while a glass capillary viscometer provides the efflux time which is related with the kinematic viscosity. Experimental densities and 5 viscosities of the pure components agree with data reported in the literature within an average absolute percentage deviation of 0.03% and 1.16%, respectively. The excess molar volumes and viscosity deviation calculated from experimental data present negative deviations from ideality in the entire temperature range. The Redlich-Kister equation is used to represent the composition behavior of excess molar volumes and the viscosity deviations. The Nava-Rios equation correlates our kinematic viscosity data within an overall average absolute percentage correlates the kinematic viscosity within 1.541%.