Radio-cesium constitutes major environmental threats. Sorption of hazardous species onto geopolymeric sorbents is relatively recent and may give information about the retention mechanisms when geopolymers are applied to immobilize radwastes. Here, Na-MK, K-MK, Na-MKBFS, and K-MKBFS geopolymeric sorbents were synthesized from metakaolin (MK) and blast furnace slag (BFS) and were characterized using XRD, XRF, FT-IR, DTA/TGA and SEM. FT-IR/XRF results clarified the impact of mono-valent alkali cation (M+) in dividing the sorbents into Al-rich (sodium-based) and Si-rich (potassium-based). All sorbents were amorphous to semi-crystalline containing mica-phyllosilicates (greater in Si-rich), tobermorites (greater in MKBFS-based), gehlenite, calcite, quartz, hematite and hydrotalcite. Isotherms of Cs-134 radionuclide sorption were constructed, being regular with a positive temperature effect. Al-rich sorbents gave higher sorption capacities than Si-rich ones. Na-MK sorbent recorded the more distinctive sorption capacity (74.95 mg/g; at 333K). Langmuir, Freundlich and D-R models were used to disclose the capacities and mechanisms governing the sorption processes. Sorption of Cs+ onto the examined sorbents was favorable. All systems were controlled by ion exchange mechanism, except Cs-134/K-MK system which was controlled by physi-sorption mechanism. Cs-134/Na-MK GP system was the only spontaneous among all. The endothermic natures were the common denominator between the tested systems. (C) 2017 Elsevier B.V. All rights reserved.