화학공학소재연구정보센터
Journal of Polymer Science Part B: Polymer Physics, Vol.56, No.3, 239-247, 2018
Fast and excellent healing of hydroxypropyl guar gum/poly(N,N-dimethyl acrylamide) hydrogels
In this article, a fast and high efficient healing hydroxypropyl guar gum (HPG)/poly(N,N-dimethyl acrylamide) (PDMA) hydrogel is prepared by a facile synthesis method. HPG networks are formed through hydrogen-bond interaction between the hydroxyl groups in the HPG chains, and PDMA networks are self-crosslinked without any chemical crosslinker. The cut hydrogel could heal when nanosilica solution is chosen as the connector that is related to the adsorption of polymer to the surface of nanosilica. The fracture stress of the HPG/PDMA gels presents a fast and almost full recovery within a short time (1 min), while the recovery of fracture strain and elastic modulus is related to time in 2 h. The healing efficiency of HPG/PDMA gel is investigated as a function of healing time, HPG content, and N,N-dimethyl acrylamide content. The microscopic healing process and healing mechanism are also discussed. (c) 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2018, 56, 239-247