In-situ volume, pressure and thickness measurements were performed on Li-ion pouch cells with various silicon-composite negative electrodes to quantify electrode volume expansion. Li(Ni1-x-yCoxAly)O-2/SiO-graphite, LiCoO2/Si Alloy-graphite and Li(Ni1-x-yCoxAly)O-2/nano Si-C pouch cells were tested in this work. Archimedes-type in-situ volume measurements and in-situ thickness measurements showed cell expansion during charge and contraction during discharge due to electrode lithiation and de-lithiation. An in-situ pressure measurement was used to measure the effect of electrode volume expansion on volumetrically-constrained pouch cells. The volume expansion and contraction profiles measured exhibit a non-linear, asymmetric behavior as a function of cell state of charge for all cell types. To explain this, calculations of the volume expansion contribution of each electrode component were performed. Based on the results of the calculations, conclusions about the mechanisms contributing to the measured expansion profiles can be made. (C) The Author(s) 2017. Published by ECS. All rights reserved.