A liquid crystalline polymethacrylate having two cyclohexylphenyl mesogens on its side-chain (PMG0) was synthesized by the radical polymerization of the corresponding methacrylate monomer (MG0). PMG0 exhibited a smectic A phase around room temperature showing a focalconic fan texture in POM observations and a broad diffusion in a wide angle range of its WAXD profile. Upon slow cooling at -1 degrees C min-1 from the isotropic melt, PMG0 exhibited spontaneous homeotropic alignment between two native glass surfaces. A mixture of the commercial nematic liquid crystal (ZLI-4792) containing 1.0 wt% PMG0 also exhibited a homeotropic alignment, which easily covered hydrophilic surfaces such as glass or polyacrylamide.