In this work, a canny combination of thiophe-phenylquinoline based red emitting heteroleptic Ir(III) complexes have been synthesized and used for solution processed phosphorescent organic light-emitting diode applications (PhOLEDs). The thermal stabilities, photophysical properties, electrochemical behaviors and electroluminescence properties are systematically investigated. An easy synthetic pathway is followed for preparing heteroleptic bis(2-(benzothiophen-2- yl)-4-phenylquinoline) iridium picolinicacid (BTPQ)(2)Ir(pic) and bis(2-(benzothiophen-2-yl)-4-phenylquinoline) iridium acetylacetate (BTPQ)(2) Ir(acac) complexes. The NIR PhOLEDs were fabricated with the configuration of ITO/ PEDOT:PSS (40 nm)/TCTA:TPBI:Ir(III) complexes (40 nm)/TmPyPB (20 nm)/LiF (1 nm)/Al (100 nm). The optimized red PhOLEDs showedmaximum external quantum efficiency of 11.23% with stable NIR CIE coordinates (0.706, 0.277).