화학공학소재연구정보센터
Polymer, Vol.134, 71-74, 2018
Linear rheology of natural rubber compounds filled with silica, short nylon fiber or both
Engineered rubbery materials in practical applications usually contain nanoparticle and microscopic short fiber while no theories could describe the viscoelasticity of the compounds varying with these two kinds of fillers. We describe how the linear rheology of natural rubber compounds varies with the loading of precipitated silica, short nylon fiber, or both. We for the first time disclose a filler dimension-dependent hydrodynamic-to-non-hydrodynamic transition by applying the time-concentration super-position principle for accounting for the apparent liquid-to-solid transition related to filler composition and loading and the retarded dynamics of the matrix. A framework for simultaneous solving the reinforcement and dissipation of the multi-component compounds is suggested, providing a new perspective on understanding the filling effect for manufacturing high-performance rubber materials. (C) 2017 Elsevier Ltd. All rights reserved.