In this work, we report on the passivation of porous silicon (PS) by tungsten trioxide (WO3) nanostructured thin films deposited via dip-coating of PS in tungsten hexachloride and water/ethanol solution. Structural analysis by Fourier transform infrared spectroscopy showed a partial disappearance of SiHx and Si-O-Si peaks after WO3 thin film deposition on the PS due to the replacement of H atoms by WO3. Additionally, PS/WO3 sample revealed weakly intense peaks which can be ascribed to O-W-O and W=O bridging bonds. Morphological analysis by atomic force spectroscopy showed the coverage of the PS surface by a nanostructured thin film of dense WO3 nanoparticles with a size ranging from 40 to 60 nm. The photoluminescence signal intensity of PS/WO3 samples presents a continuous increase as a function of the immersion time in the precursor solution. This is attributed to a better decoration of the PS surface by WO3 nanoplatelets and a decrease of surface recombination velocity (200 x 10(2) cm/s for untreated silicon, 137 x10(2) cm/s for PS and 99 x10(2) cm/s for PS/WO(3)samples). Hence, a similar to 50% improvement in the effective lifetime of minority carriers is obtained. Moreover, the deposited WO3 contributed not only to the passivation of PS, but acted as an antireflection layer which enhanced the optical properties of PS by reducing the reflection of light. These obtained results confirmed the benefits of using WO3 thin film as passivation/antireflection coating for possible solar cell application.