Separation of gold(III) from hydrochloric acid solution containing platinum(IV) and palladium(II) by solvent extraction with Cyanex 272 and LIX 63

Wei Dong Xing; Man Seung Lee; Young Hwan Kim

Journal of Industrial and Engineering Chemistry, Vol.59, 328-334, March, 2018

DOI10.1016/j.jiec.2017.10.039 Export Citation

Separation of gold(III) from hydrochloric acid solution containing platinum(IV) and palladium(II) by solvent extraction with Cyanex 272 and LIX 63

Wei Dong Xing, Man Seung Lee^†, and Young Hwan Kim¹

Department of Advanced Material Science & Engineering, Institute of Rare Metal, Mokpo, National University, Chonnam 534-729, Republic of Korea
¹Research Institute of Advanced Manufacturing Technology, Korea Institute of Industrial Technology, Incheon 21999, Republic of Korea

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Solvent extraction experiments were performed to separate Au(III), Pt(IV) and Pd(II) in the HCl concentration ranged from 0.5 to 9 M. Cyanex 272 extracted only Au(III) among the three metals, while both Au(III) and Pd(II) was extracted by LIX 63 in the experimental ranges. The Au(III) in the loaded Cyanex 272 and LIX63 was stripped by either (NH4)2S2O3 or (NH2)2CS. The concentration ratio of Au(III) to Pd(II) affected the extraction behavior of Au(III) and Pd(II) by LIX 63. The characteristic vibration bands of Cyanex 272 and LIX 63 were proposed by analyzing the FT-IR.

Keywords:Solvent extraction,Gold;Hydrochloric acid;Cyanex 272;LIX 63

[References]

Syed S, Hydrometallurgy, 115-116, 30 (2012)
Fujiwara K, Ramesh A, Maki T, Hasegawa H, Ueda K, J. Hazard. Mater., 146(1-2), 39 (2007)
Ramesh A, Hasegawa H, Sugimoto W, Maki T, Ueda K, Bioresour. Technol., 99(9), 3801 (2008)
Ahamed MEH, Mbianda XY, Mulaba-Bafubiandi AF, Marjanovic L, Hydrometallurgy, 140, 1 (2013)
Nguyen VT, Lee JC, Jeong J, Kim BS, Cote G, Chagnes A, Ind. Eng. Chem. Res., 54(4), 1350 (2015)
Wei W, Cho CW, Kim S, Song M, Bediako JK, Yun YS, J. Mol. Liq., 216, 18 (2016)
Papaiconomou N, Vite G, Goujon N, Leveque JM, Billard I, Green Chem., 14, 2050 (2012)
Nguyen TH, Sonu CH, Lee MS, J. Ind. Eng. Chem., 32, 238 (2015)
Akita S, Yang L, Takeuchi H, Hydrometallurgy, 43, 37 (1996)
Martlnez S, Navarro P, Sastre AM, Alguacil FJ, Hydrometallurgy, 43, 1 (1996)
Petrova AM, Nikolaev AE, Kasikov AG, Russ. J. Appl. Chem., 87, 234 (2014)
Nguyen TH, Wang L, Lee MS, Korean J. Met. Mater, 55, 247 (2017)
Shen YF, Xue WY, Sep. Purif. Technol., 56(3), 278 (2007)
Fontas C, Antico E, Vocanson F, Lamartine R, Seta P, Sep. Purif. Technol., 54(3), 322 (2007)
Kakoi T, Goto M, Nakashio F, Solvent Extr. Ion Exch., 12, 541 (1994)
H.T. Truong, M.S. Lee, Separation of Pd(II) and Pt(IV) from Hydrochloric Acid Solutions by Solvent Extraction with Cyanex 301, M.N. University Ed., 2017.
Mistry BD, Handbook of Spectroscopic Data Chemistry, 2009 edn., Oxford Book Company, Jaipur, India, 2009.
Nguyen TH, Sonu CH, Lee MS, Hydrometallurgy, 164, 71 (2016)
Alguacil FJ, Caravaca C, Hydrometallurgy, 34, 91 (1993)
Alguacil FJ, Solvent Extr. Ion Exch., 21, 841 (2003)
Barroso MA, Lopez FA, Sastre A, Alguacil FJ, Hydrometallurgy, 45, 199 (1997)
Martfnez S, Sastre A, Alguacil FJ, Hydrometallurgy, 46, 205 (1997)
SarKar SG, Dhadke PM, J. Chin. Chem. Soc., 47, 869 (2000)
Lu WJ, Lu YM, Liu F, Shang K, Wang W, Yang YZ, J. Hazard. Mater., 186(2-3), 2166 (2011)
Mowafy EA, Mohamed D, Sep. Purif. Technol., 167, 146 (2016)

[Referenced By]

[1] Syed S, Hydrometallurgy, 115-116, 30 (2012)

[2] Fujiwara K, Ramesh A, Maki T, Hasegawa H, Ueda K, J. Hazard. Mater., 146(1-2), 39 (2007)

[3] Ramesh A, Hasegawa H, Sugimoto W, Maki T, Ueda K, Bioresour. Technol., 99(9), 3801 (2008)

[4] Ahamed MEH, Mbianda XY, Mulaba-Bafubiandi AF, Marjanovic L, Hydrometallurgy, 140, 1 (2013)

[5] Nguyen VT, Lee JC, Jeong J, Kim BS, Cote G, Chagnes A, Ind. Eng. Chem. Res., 54(4), 1350 (2015)

[6] Wei W, Cho CW, Kim S, Song M, Bediako JK, Yun YS, J. Mol. Liq., 216, 18 (2016)

[7] Papaiconomou N, Vite G, Goujon N, Leveque JM, Billard I, Green Chem., 14, 2050 (2012)

[8] Nguyen TH, Sonu CH, Lee MS, J. Ind. Eng. Chem., 32, 238 (2015)

[9] Akita S, Yang L, Takeuchi H, Hydrometallurgy, 43, 37 (1996)

[10] Martlnez S, Navarro P, Sastre AM, Alguacil FJ, Hydrometallurgy, 43, 1 (1996)

[11] Petrova AM, Nikolaev AE, Kasikov AG, Russ. J. Appl. Chem., 87, 234 (2014)

[12] Nguyen TH, Wang L, Lee MS, Korean J. Met. Mater, 55, 247 (2017)

[13] Shen YF, Xue WY, Sep. Purif. Technol., 56(3), 278 (2007)

[14] Fontas C, Antico E, Vocanson F, Lamartine R, Seta P, Sep. Purif. Technol., 54(3), 322 (2007)

[15] Kakoi T, Goto M, Nakashio F, Solvent Extr. Ion Exch., 12, 541 (1994)

[16] H.T. Truong, M.S. Lee, Separation of Pd(II) and Pt(IV) from Hydrochloric Acid Solutions by Solvent Extraction with Cyanex 301, M.N. University Ed., 2017.

[17] Mistry BD, Handbook of Spectroscopic Data Chemistry, 2009 edn., Oxford Book Company, Jaipur, India, 2009.

[18] Nguyen TH, Sonu CH, Lee MS, Hydrometallurgy, 164, 71 (2016)

[19] Alguacil FJ, Caravaca C, Hydrometallurgy, 34, 91 (1993)

[20] Alguacil FJ, Solvent Extr. Ion Exch., 21, 841 (2003)

[21] Barroso MA, Lopez FA, Sastre A, Alguacil FJ, Hydrometallurgy, 45, 199 (1997)

[22] Martfnez S, Sastre A, Alguacil FJ, Hydrometallurgy, 46, 205 (1997)

[23] SarKar SG, Dhadke PM, J. Chin. Chem. Soc., 47, 869 (2000)

[24] Lu WJ, Lu YM, Liu F, Shang K, Wang W, Yang YZ, J. Hazard. Mater., 186(2-3), 2166 (2011)

[25] Mowafy EA, Mohamed D, Sep. Purif. Technol., 167, 146 (2016)