Journal of Industrial and Engineering Chemistry, Vol.59, 335-340, March, 2018
Inverted polymer solar cells with brush-painted ZnO electron transport layer
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Air-stable inverted polymer solar cells (IPSCs) were demonstrated by incorporating ZnO electron transport layer (ETL) fabricated with low-cost and simple brush-painting. IPSC with brush-painted ZnO using commonly used 0.75 M zinc acetate solution in 95% 2-methoxyethanol and 5% ethanolamine showed poor efficiency and reproducibility. By optimizing precursor solution and substrate temperature, thieno[3,4-b]thiophene/benzodithiophene (PTB7): [6,6]-phenyl C71-butyric acid methyl ester (PC71BM) based IPSC with high power conversion efficiency (PCE) of 7.63% and desirable device stability was achieved. This indicates that because optimized process conditions are not necessarily transferrable between different techniques, it is worthy of investigation and discussion.
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