화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.60, 206-217, April, 2018
DOI10.1016/j.jiec.2017.11.008  Export Citation
Double-layered core-shell structure of NaYF4:Yb,Er@SiO2@Zn1-xMnxO for near-infrared-triggered photodegradation and antibacterial application
Linxiang Tan, Xiaoxia Ke, Xuechun Song, Qiaoqiao Yin, Ru Qiao†, Kaiyan Guo, and Lanlan Zhu
  • Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, College of Chemistry and Life Sciences, Zhejiang Normal University, Jinhua 321004, China
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A novel NIR-responsive photocatalyst NaYF4:Yb,Er@SiO2@Zn1 -xMnxO with double-layered core.shell structure was prepared by a three-step reaction. NaYF4:Yb,Er serves as a NIR-to-visible upconverter and provides “visible light” or “necessary energy” to Zn1 -xMnxO. Meanwhile, Mn2+-doping in Zn1 -xMnxO can extend the photoresponse of ZnO to visible-light region and enhance its charge separation. The nanocomposite exhibits good activity for dye decomposition and antibacterial property under NIR irradiation. The “energy absorption - energy conversion energy transfer - surface reaction” process dominates the overall photocatalytic -activity. Based on the standard MTT (abbr. for 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyl tetrazolium bromide) assay, NaYF4:Yb,Er@SiO2@Zn1 -xMnxO also exhibits good biocompatibility and low cytotoxicity with human umbilical vein endothelial cells (HUVEC) as model cells.
Keywords:Upconversion;Mn-doped ZnO;Core.shell structure;Photocatalytic activity;Biocompatibility
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