Facile synthesis and characterization of γ-AlOOH/PVA composite granules for Cr(VI) adsorption

The Ky Vo; Hyung-Kyu Park; Chul-Woo Nam; Sung-Don Kim; Jinsoo Kim

Journal of Industrial and Engineering Chemistry, Vol.60, 485-492, April, 2018

DOI10.1016/j.jiec.2017.11.036 Export Citation

Facile synthesis and characterization of γ-AlOOH/PVA composite granules for Cr(VI) adsorption

The Ky Vo, Hyung-Kyu Park¹, Chul-Woo Nam¹, Sung-Don Kim^{1, †}, and Jinsoo Kim^†

Department of Chemical Engineering, Kyung Hee University, 1732 Deogyeong-daero, Giheung-gu, Yongin, Gyeonggi-do 17104, Republic of Korea
¹Mineral Resources Research Division, Korea Institute of Geoscience and Mineral Resources, 124 Gwahak-ro, Yuseong-gu, Daejeon 34132, Republic of Korea

E-mail:,

γ-AlOOH(boehmite)/PVA composite granules with high adsorption performance towards Cr(VI) were successfully synthesized by combining sol.gel and oil-drop methods. The γ-AlOOH/PVA sample with 35 wt% PVA showed the highest Cr(IV) adsorption capacity of 35.91 mg/g, which was much higher than that of the pure γ-AlOOH sample (17.08 mg/g). The adsorption behaviors of Cr(VI) ions onto the γ-AlOOH and γ-AlOOH/PVA granules were well described by the pseudo-second-order kinetic model, and the adsorption mechanisms included electrostatic attraction, ligand exchange and redox reaction. The recovery of Cr(VI) under basic conditions was conducted to evaluate the practical utility of the synthesized composite granules.

Keywords:Boehmite;PVA;Chromium;Oil-drop;Adsorbent

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[Referenced By]

[1] Glorias-Garcia F, Arriaga-Merced JM, Roa-Morales G, Varela-Guerrero V, Barrera-Diaz CE, Bilyeu B, J. Ind. Eng. Chem., 20(4), 2477 (2014)

[2] Wu S, Lu J, Ding Z, Li N, Fu F, Tangl B, RSC Adv., 6, 82118 (2016)

[3] Khitous M, Salem Z, Halliche D, Korean J. Chem. Eng., 33(2), 638 (2016)

[4] Pradhan D, Sukla SB, Sawyer M, Rahman PKSM, J. Ind. Eng. Chem., 55, 1 (2017)

[5] Barrera-Diaz CE, Lugo-Lugo V, Bilyeul B, J. Hazard. Mater., 223-224, 1 (2012)

[6] Lopez-Tellez G, Barrera-Diaz CE, Balderas-Hernandez P, Roa-Morales G, Bilyeu B, Chem. Eng. J., 173(2), 480 (2011)

[7] Tytłak A, Oleszczuk P, Dobrowolskil R, Environ. Sci. Pollut. Res. Int, 22, 5985 (2015)

[8] Luo L, Cai WQ, Zhou JB, Li YZ, J. Hazard. Mater., 318, 452 (2016)

[9] Werkneh NHAA, Beyenel HD, AJAC, 2, 128 (2014)

[10] Gottipati R, Mishra S, J. Ind. Eng. Chem., 36, 355 (2016)

[11] Mishra S, Verma N, J. Ind. Eng. Chem., 36, 346 (2016)

[12] Yongqiang W, Guozhong W, Hongqiang W, Weiping C, Changhao L, Lidel Z, Nanotechnology, 20, 155604 (2009)

[13] Fan Y, Yang R, Lei Z, Liu N, Lv J, Zhai S, Zhai B, Wang L, Korean J. Chem. Eng., 33(4), 1416 (2016)

[14] Yang X, Wang X, Feng Y, Zhang G, Wang T, Song W, Shu C, Jiang L, Wangl C, J. Mater. Chem. A, 1, 473 (2013)

[15] Mohamadi Z, Abdolmaleki A, J. Ind. Eng. Chem., 55, 164 (2017)

[16] Granados-Correa F, Jimenez-Becerril J, J. Hazard. Mater., 162(2-3), 1178 (2009)

[17] Alphonse P, Courty M, Thermochim. Acta, 425(1-2), 75 (2005)

[18] Hallajiqomi M, Eisazadeh H, J. Ind. Eng. Chem., 55, 191 (2017)

[19] Sugumaran S, Bellanl CS, Optik, 125, 5128 (2014)

[20] Jensen BEB, Alves MH, Fejerskov B, Stadler B, Zelikinl AN, Soft Matter, 8, 4625 (2012)

[21] Yang ZH, Lin YS, Ind. Eng. Chem. Res., 39(12), 4944 (2000)

[22] Choi J, Kim J, Yoo KS, Lee TG, Powder Technol., 181(1), 83 (2008)

[23] Ren Z, Kong D, Wang K, Zhangl W, J. Mater. Chem. A, 2, 17952 (2014)

[24] Li P, Zheng S, Qing P, Chen Y, Tian L, Zheng X, Zhangl Y, Green Chem., 16, 4214 (2014)

[25] Zhang H, Li P, Wang Z, Zhang X, Zheng S, Zhangl Y, ACS Sustain. Chem. Eng., 5, 6674 (2017)

[26] Mansur HS, Sadahira CM, Souza AN, Mansurl AAP, Mater. Sci. Eng. C-Biomimetic Supramol. Syst., 28, 539 (2008)

[27] Zhu YY, Jiang ZY, Zhang L, Shi JF, Yang D, Ind. Eng. Chem. Res., 51(1), 255 (2012)

[28] Yang WP, Shyu SS, Lee ES, Chaol AC, Mater. Chem. Phys., 45, 108 (1996)

[29] Ho YS, McKay G, Process Saf. Environ. Protect., 76(4), 332 (1998)

[30] Gunasundari E, Kumar PS, J. Ind. Eng. Chem., 56, 129 (2017)

[31] Deravanesiyan M, Beheshti M, Malekpour A, J. Ind. Eng. Chem., 21, 580 (2015)

[32] Ji M, Su X, Zhao YX, Qi WF, Wang Y, Chen GY, Zhang ZY, Appl. Surf. Sci., 344, 128 (2015)

[33] Zhang YJ, Ou JL, Duan ZK, Xing ZJ, Wangl Y, Colloids Surf. A: Physicochem. Eng. Asp., 481, 108 (2015)

[34] Li WG, Gong XJ, Li X, Zhang DY, Gong HN, Bioresour. Technol., 113, 106 (2012)

[35] Saeed A, Akhter MW, Iqbal M, Sep. Purif. Technol., 45(1), 25 (2005)

[36] Bai RS, Abraham TE, Bioresour. Technol., 87(1), 17 (2003)

[37] Wei LS, Yang G, Wang R, Ma W, J. Hazard. Mater., 164(2-3), 1159 (2009)

[38] Bankar AV, Kumar AR, Zinjarde SS, J. Hazard. Mater., 170(1), 487 (2009)