화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.61, 304-313, May, 2018
DOI10.1016/j.jiec.2017.12.028  Export Citation
Cu-loaded ZSM-5 zeolites: An ultra-sensitive phenolic sensor development for environmental safety
Mohammed M. Rahman†, Bahaa M. Abu-Zied, and Abdullah M. Asiri
  • Center of Excellence for Advanced Materials Research (CEAMR) & Chemistry Department, Faculty of Science, King Abdulaziz University, P.O. Box 80203, Jeddah 21589, Saudi Arabia
E-mail:
Various copper loaded ZSM-5 zeolites was prepared and characterized in details of their optical, structural, morphological, elemental properties by various conventional methods. The Cu-ZSM-5 zeolites were deposited on silver electrode to result in a chemical sensor that has a fast response to selective 3-methoxyphenol (3-MP) in buffer phase. Analytical sensor parameters such as sensitivity, detection limit, reproducibility, selectivity, repeatability, linear dynamic range, and electrochemical performances were investigated in details with the Cu-ZSM-5 zeolites fabricated sensors. The calibration plot is linear over the large 3-MP concentration range. The sensitivity and detection limit of target 3-MP is calculated as ~13.232 μA cm-2mM-1 and 0.083 ±0.002 nM (at a signal-to-noise-ratio, SNR of 3) respectively. With such excellent features as wide linear dynamic range, higher sensitivity, good stability, lowest detection limit, excellent selectivity, the developed sensor provides a new strategy for determination of 3-MP in biomedical and environmental sample with satisfactory results.
Keywords:Cu-ZSM-5 zeolites;3-methoxyphenol;Silver electrode;I-V technique;Environmental safety
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