화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.61, 388-397, May, 2018
Application of ionic liquids for metal dissolution and extraction
E-mail:,
This review summarizes the results of studies on the selective dissolution and extraction of Fe, Cr, Cu, and Zn by ionic liquids, as an alternative to the use of conventional molten salts or pickling agents, for various types of steel. Ionic liquids are classified according to the metals, metal ions, and metal oxides by which they can be extracted or dissolved. The results of the metal extraction efficiency per unit time presented in the literature are summarized in a simple unified graphic format. This provides a comparative understanding of the most efficient ionic liquid for the extraction of specific metals.
  1. Abbott AP, Capper G, Davies DL, Rasheed RK, Shikotra P, Inorg. Chem., 44(19), 6497 (2005)
  2. Pedrazzini C, Giordani P, Process for stainless steel pickling and passivation without using nitric acid, US 5843240 A, 1998.
  3. Li LF, Caenen P, Daerden M, Vaes D, Meers G, Dhondt C, Celis JP, Corrosion Sci., 47, 1307 (2005)
  4. American Iron and Steel Institute, Cleaning and Descaling Stainless Steels, American Iron and Steel Institute, Washington, DC, 1982.
  5. Whitehead JA, Zhang J, Pereira N, McCluskey A, Lawrance GA, Hydrometallurgy, 88, 109 (2007)
  6. Whitehead JA, Zhang J, McCluskey A, Lawrance GA, Hydrometallurgy, 98, 276 (2009)
  7. Fischer L, Falta T, Koellensperger G, Stojanovic A, Kogelnig D, Galanski M, Krachler R, Keppler BK, Hann S, Water Res., 45, 4601 (2011)
  8. Abbott AP, Barron JC, Elhadi M, Frisch G, Gurman SJ, Hillman AR, Smith EL, Mohamoud MA, Ryder KS, ECS Trans., 16, 47 (2009)
  9. Nockemann P, Thijs B, Pittois S, Thoen J, Glorieux C, Van Hecke K, Van Meervelt L, Kirchner B, Binnemans K, J. Phys. Chem. B, 110(42), 20978 (2006)
  10. Everson HE, Ilenda FP, Alkaline composition, US 2931778 A, 1954..
  11. Shanghuai Z, Pickling treatment technique for stainless steel, CN 105671566 A2014.
  12. Michiro K, Hidehiko S, Manufacture of cold-rolled stainless steel strips with high surface luster and improved corrosion resistance, JP 09041156 A, 1997.
  13. Łuczak L, Joskowska M, Hupka J, Physicochem. Probl. Miner. Process., 42, 223 (2008)
  14. Chun H, Choi S, Clean Technol., 11(1), 21 (2005)
  15. Lateef H, Grimes SM, Morton R, Mehtal L, J. Chem. Technol. Biotechnol., 83(4), 541 (2008)
  16. Hirayama N, Deguchi M, Kawasumi H, Honjo T, Talanta, 65, 255 (2005)
  17. Groshart EC, Pickling and acid dippinc, in: Wegman RF, Twisk JV (Eds.), Surface Preparation Techniques for Adhesive Bonding, second ed., Elsevier Science, NY, p. 140, 2012.
  18. Kruizenga A, Gill D, Energy Procedia, 49, 878 (2014)
  19. Dietz ML, Stepinski DC, Talanta, 75, 598 (2008)
  20. Wellens S, Hoogerstraete TV, Moller C, Thijs B, Luyten J, Binnemans K, Hydrometallurgy, 144-145, 27 (2014)
  21. Dietz ML, Dzielawa JA, Laszak I, Young BA, Jensen MP, Green Chem., 5, 682 (2003)
  22. Mehdi H, Binnemans K, Hecke KV, Meervelt LV, Nockemann P, Chem. Commun., 46, 234 (2010)
  23. Harjani JR, Friscic T, MacGillivray LR, Singer RD, Dalton Trans. (2008) 4595, doi:http://dx.doi.org/10.1039/b806369a.
  24. Gabriel S, Weiner J, Eur. J. Inorg. Chem., 21, 2669 (1888)
  25. Wilkes JS, Levisky JA, Wilson RA, Hussey CL, Inorg. Chem., 21, 1263 (1982)
  26. Hitchcock PB, Mohammed TJ, Seddon KR, Zora JA, Hussey CL, Ward EH, Inorg. Chim. Acta., 113, L25 (1986)
  27. Crofts D, Dyson PJ, Sanderson KM, Srinivasan N, Welton T, J. Organomet. Chem., 573, 292 (1999)
  28. Visser AE, Swatloski RP, Reichert WM, Mayton R, Sheff S, Wierzbicki A, Davis JH, Rogers RD, Environ. Sci. Technol., 36, 2523 (2002)
  29. Shimojo K, Goto M, Anal. Chem., 76, 5039 (2004)
  30. Whitehead JA, Lawrance GA, McCluskey A, Green Chem., 6, 313 (2004)
  31. Nockemann P, Thijs B, Parac-Vogt TN, Van Hecke K, Van Meervelt L, Tinant B, Hartenbach I, Schleid T, Ngan VT, Nguyen MT, Binnemans K, Inorg. Chem., 47(21), 9987 (2008)
  32. Papaiconomou N, Lee JM, Salminen J, von Stosch M, Prausnitz JM, Ind. Eng. Chem. Res., 47(15), 5080 (2008)
  33. Wei GT, Yang Z, Chen CJ, Anal. Chim. Acta, 488, 183 (2003)
  34. Ouadi A, Gadenne B, Hesemann P, Moreau JJE, Billard I, Gaillard C, Mekki S, Moutiers G, Chem. Eur. J., 12, 3074 (2006)
  35. Rout A, Venkatesan K, Srinivasan T, Radiochim. Acta, 97, 719 (2009)
  36. Visser AE, Rogers RD, J. Solid State Chem., 171, 109 (2003)
  37. Rout A, Venkatesan KA, Srinivasan TG, Radiochim. Acta, 98, 459 (2010)
  38. He Q, Zhang Y, Nie L, J. Rare Earths, 25, 152 (2007)
  39. Wu B, Reddy R, Rogers R, Production, refining and recycling of lightweight and reactive metals in ionic liquids, US 20040238352 A1, 2004, http://www.google.com/patents/US20040238352 (Accessed 24 May 2017).
  40. Jiang-hua M, Yu-ping L, Hui-quan L, Yi Z, Chin. J. Process Eng., 7, 1083 (2007)
  41. de los Rios AP, Hernandez-Fernandez FJ, Alguacil FJ, Lozano LJ, Ginesta A, Garcia-Diaz I, Sanchez-Segado S, Lopez FA, Godinez C, Sep. Purif. Technol., 97, 150 (2012)
  42. Abbott AP, Capper G, Davies DL, McKenzie KJ, Obi SU, J. Chem. Eng. Data, 51(4), 1280 (2006)
  43. Kozonoi N, Ikeda Y, Monatsh. Chem., 138, 1145 (2007)
  44. Visser AE, Swatloski RP, Griffin ST, Hartman DH, Rogers RD, Sep. Sci. Technol., 36(5-6), 785 (2001)
  45. Visser AE, Swatloski RP, Reichert WM, Mayton R, Sheff S, Wierzbicki A, Davis JH, Rogers RD, Chem. Commun. (2001) 135, doi:http://dx.doi.org/10.1039/B008041L.
  46. de los Rios AP, Hernandez-Fernandez FJ, Lozano LJ, Sanchez S, Moreno JI, Godinez C, J. Chem. Eng. Data, 55(2), 605 (2010)
  47. Renner R, Ionic liquids: an industrial cleanup solution, Environmental Science & Technology, ACS Publications, 2001, doi:http://dx.doi.org/10.1021/es012505a p. 410A.
  48. Mahandra H, Singh R, Gupta B, Sep. Purif. Technol., 177, 281 (2017)
  49. Zuo Y, Chen J, Bai Y, Li DQ, Metallurgy and Petroleum, Montreal, Quebec (Canada), Arizona, pp. 1195, 2008. https://www.osti.gov/scitech/biblio/21230398 (Accessed 29 May 2017).
  50. Zuo Y, Liu Y, Chen J, Li DQ, J. Chem. Technol. Biotechnol., 84(7), 949 (2009)
  51. Zuo Y, Liu Y, Chen J, Li DQ, Ind. Eng. Chem. Res., 47(7), 2349 (2008)
  52. Nakashima K, Kubota F, Maruyama T, Goto M, Ind. Eng. Chem. Res., 44(12), 4368 (2005)
  53. Luo H, Dai S, Bonnesen PV, Buchanan AC, Holbrey JD, Anal. Chem., 76, 3078 (2004)
  54. Nakashima K, Kubota F, Maruyama T, Goto M, Anal. Sci., 19, 1097 (2003)
  55. Zuo Y, Chen J, Li DQ, Sep. Purif. Technol., 63(3), 684 (2008)
  56. Zhang C, Chen J, Zhou Y, Li D, J. Phys. Chem. C, 112, 10083 (2008)
  57. Chen J, Sun X, Peng B, producing method and application thereof, CN 101274154, 2007.
  58. Wellens S, Thijs B, Moller C, Binnemans K, Phys. Chem. Chem. Phys., 15, 9663 (2013)
  59. Hoogerstraete TV, Wellens S, Verachtert K, Binnemans K, Green Chem., 15, 919 (2013)
  60. Vidal STM, Correia MJN, Marques MM, Ismael MR, Reis MTA, Sep. Sci. Technol., 39(9), 2155 (2004)
  61. Dupont D, Raiguel S, Binnemans K, Chem. Commun., 51, 9006 (2015)
  62. Sadeghi S, Moghaddam AZ, J. Mol. Liq., 221, 798 (2016)
  63. Sadeghi S, Moghaddam AZ, Talanta, 99, 758 (2012)
  64. Visser AE, Swatloski RP, Reichert WM, Griffin ST, Rogers RD, Ind. Eng. Chem. Res., 39(10), 3596 (2000)
  65. Luo H, Dai S, Bonnesen PV, Anal. Chem., 76, 2773 (2004)
  66. Chen PY, Electrochim. Acta, 52(17), 5484 (2007)
  67. Chun S, Dzyuba SV, Bartsch RA, Anal. Chem., 73, 3737 (2001)
  68. Luo H, Dai S, Bonnesen PV, Bonnesen AC, J. Alloy. Compd., 418, 195 (2006)
  69. Egorov VM, Djigailo DI, Momotenko DS, Chernyshov DV, Torochesh-nikova II, Smirnova SV, Pletnev IV, Talanta, 80, 1177 (2010)
  70. Wei GT, Chen JC, Yang Z, J. Chin. Chem. Soc., 50, 1123 (2003)
  71. Shimojo K, Kurahashi K, Naganawa H, Dalton Trans., 5083 (2008), doi:http://dx.doi.org/10.1039/b810277p.
  72. Jensen MP, Neuefeind J, Beitz JV, Skanthakumar S, Soderholm L, J. Am. Ceram. Soc., 125, 15466 (2003)
  73. Sun XQ, Peng B, Ji Y, Chen J, Li DQ, Sep. Purif. Technol., 63(1), 61 (2008)
  74. Sun XQ, Peng B, Chen J, Li DQ, Luo F, Talanta, 74, 1071 (2008)
  75. Yinghui L, Xiaoqi S, Fang L, Ji C, Chin. J. Rare Met., 31, 395 (2007)
  76. Germani R, Mancini MV, Savelli G, Spreti N, Tetrahedron Lett., 48, 1767 (2007)
  77. Sun XQ, Wu DB, Chen J, Li DQ, J. Chem. Technol. Biotechnol., 82(3), 267 (2007)
  78. Dietz ML, Jakab S, Yamato K, Bartsch RA, Green Chem., 10, 174 (2008)
  79. Zaijun L, Qiping P, Haixia S, J. AOAC Int., 90, 1191 (2007)
  80. Abbott AP, Capper G, Davies DL, Shikotra P, Trans. Inst. Min. Metall. C, 115, 15 (2006)
  81. Lohithakshan KV, Aggarwal SK, Radiochim. Acta, 96, 93 (2008)
  82. Xiaoqi S, Bo P, Ji C, Deqian L, J. Chin. Rare Earth Soc., 25, 417 (2007)
  83. Dai S, Ju YH, Barnes CE, J. Chem. Soc. Dalton Trans., 2, 1201 (1999)
  84. Dietz ML, Dzielawa JA, Chem. Commun., 2124 (2001).
  85. Stepinski DC, Jensen MP, Dzielawa JA, Dietz ML, Green Chem., 7, 151 (2005)
  86. Ouadi A, Klimchuk O, Gaillard C, Billard I, Green Chem., 9, 1160 (2007)
  87. Billard I, Ouadi A, Jobin E, Champion J, Gaillard C, Georg S, Solvent Extr. Ion Exch., 29, 577 (2011)
  88. Dai S, Shin YS, Toth LM, Barnes CE, Inorg. Chem., 36(21), 4900 (1997)
  89. Chen J, Li DQ, Acta Chem. Proc., 54 (2008).
  90. Peng B, Sun X, Chen J, J. Rare Earths, 25, 153 (2007)
  91. Abdolmohammad-Zadeh H, Sadeghi GH, Anal. Chim. Acta, 649, 2011
  92. Home | worldsteel, https://www.worldsteel.org/ (Accessed 24 May 2017).
  93. Anderson JL, Armstrong DW, Wei G, Annu. Rev. Anal. Chem., 2, 145 (2009)
  94. Jianwei F, Jie Z, Xianghu L, Yu S, Wei C, Rongxing P, Recycling method of waste acid from stainless steel acid washing process, CN101705495 A, 2009.
  95. Chromite, https://en.wikipedia.org/wiki/Chromite (Accessed 24 May 2017).
  96. Stoeppler M, Hazardous Metals the Environment, 1st ed., Elsevier Science, Julich, 1992.
  97. Austenitic stainless steel, https://en.wikipedia.org/wiki/Austenitic_stain-less_steel (Accessed 24 May 2017).
  98. Shen H, Forssberg E, Waste Manage., 23, 933 (2003)
  99. Basir SMA, Rabah MA, Hydrometallurgy, 53, 31 (1999)
  100. Bydałek AW, Bydałek A, Arch. Foundry Eng., 14, 21 (2014)
  101. Kogelnig D, Stojanovic A, Jirsa F, Korner W, Krachler R, Keppler BK, Sep. Purif. Technol., 72(1), 56 (2010)
  102. Dimitrijevic M, Kostov A, Tasic V, Milosevic N, J. Hazard. Mater., 164(2-3), 892 (2009)
  103. Global lead seen in surplus in 2016, zinc in deficit.ILZSG | Reuters, http://www.reuters.com/article/metals-ilzsg-balance-idUSL5N17V3RA (Accessed24 May 2017).
  104. Svens K, Kerstiens K, Runkel M, Erzmetall, 56, 94 (2003)
  105. Incorporated B, Accelerating Ionic Liquid Commercialization, 2004.
  106. Zhai H, Rubin ES, Energy Procedia, 114, 2166 (2017)
  107. Chen L, Sharifzadeh M, Mac Dowell N, Welton T, Shah N, Hallett JP, Green Chem., 16, 3098 (2014)
  108. Kuzmina O, Economical aspects of ionic liquid application, Application, Purification, and Recovery of Ionic Liquids, Elsevier B.V., Oxford, London, 2016, doi:http://dx.doi.org/10.1016/B978-0-444-63713-0.00006-7 p. 249.