화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.35, No.5, 1128-1136, May, 2018
DOI10.1007/s11814-018-0017-9  Export Citation
Effect of dissolved oxygen/nZVI/persulfate process on the elimination of 4-chlorophenol from aqueous solution: Modeling and optimization study
Mansour Baziar1, Ramin Nabizadeh1, 2, †, Amir Hossein Mahvi1, Mahmood Alimohammadi1, Kazem Naddafi1, Alireza Mesdaghinia1, and Hassan Aslani3
  • 1Department of Environmental Health Engineering, School of Public Health,, Tehran University of Medical Sciences, Tehran, Iran
  • 2Center for Air Pollution Research, Institute for Environmental Research, Tehran University of Medical Sciences, Tehran, Iran
  • 3Department of Environmental Health Engineering, School of Public Health, Tabriz University of Medical Sciences, Tabriz, Iran
E-mail:
4-Chlorophenol (4-CP) is a hazardous and toxic chemical that enters into water bodies mainly through industrial effluents. The present study investigated the effect of under pressure dissolved oxygen on 4-CP degradation in the presence of nanoscale zero-valent iron (nZVI) and sodium persulfate. The impact of oxygen pressure, as a qualitative variable at three levels (1, 1.5 and 2 atm), along with five quantitative variables, including persulfate concentration (0-2mM), nZVI dosage (0-1 g/L), pH (3-11), reaction time (5-90min) and 4-CP concentration (50-500mg/L) on the 4-CP elimination from aqueous solutions, was examined using response surface methodology. There was a direct relationship between the dissolved oxygen under pressure and the 4-CP removal efficiency. Also, the gained R2 and adjusted R2 for three developed models of 1, 1.5 and 2 atm oxygen pressure were 0.971 and 0.9569, 0.9689 and 0.9538, and 0.9642 and 0.9468, respectively. The best removal process conditions for pH 4.2, 1.6mM persulfate, 64.79 min reaction time, 97.89mg/L initial 4-CP and 1 g/L nZVI dosage. The results indicated that dissolved oxygen under pressure-nZVI-persulfate could be considered a promising process for elimination of organic compounds from aqueous solutions.
Keywords:Persulfate;nZVI;Under Pressure Dissolved Oxygen;RSM
  1. Alimoradzadeh R, Assadi A, Nasseri S, Mehrasbi MR, J. Environ. Health Sci. Eng., 9(1), 12 (2012)
  2. Catrinescu C, Arsene D, Teodosiu C, Appl. Catal. B: Environ., 101(3-4), 451 (2011)
  3. Abussaud B, Asmaly HA, Saleh TA, Gupta VK, Atieh MA, J. Mol. Liq., 213, 351 (2016)
  4. Deka B, Bhattacharyya K, J. Environ. Manage., 150, 479 (2015)
  5. Liu X, Fan JH, Ma LM, Chem. Eng. J., 236, 274 (2014)
  6. Karthikeyan S, Boopathy R, Gupta VK, Sekaran G, J. Mol. Liq., 177, 402 (2013)
  7. Sze MFF, McKay G, Water Res., 46(3), 700 (2012)
  8. Sirvent G, Sanchez JM, Salvado V, J. Separation Sci., 27(17-18), 1524 (2004)
  9. Bustos-Ramirez K, Barrera-Diaz CE, De Icaza-Herrera M, Martinez-Hernandez AL, Natividad-Rangel R, Velasco-Santos C, J. Environ. Health Sci. Eng., 13(1), 33 (2015)
  10. Ahlborg UG, Thunberg TM, Spencer HC, CRC Critical Reviews in Toxicol., 7(1), 1 (1980)
  11. Shinde SS, Bhosale CH, Rajpure KY, J. Mol. Catal. A-Chem., 347(1-2), 65 (2011)
  12. Asmaly HA, Saleh TA, Laoui T, Gupta VK, Atieh MA, J. Mol. Liq., 206, 176 (2015)
  13. Karimaei M, Sharafi K, Moradi M, Ghaffari HR, Biglari H, Arfaeinia H, Fattahi N, Anal. Methods, 9(19), 2865 (2017)
  14. Mittal A, Mittal J, Malviya A, Kaur D, Gupta VK, J. Colloid Interface Sci., 343(2), 463 (2010)
  15. Mittal A, Kaur D, Malviya A, Mittal J, Gupta VK, J. Colloid Interface Sci., 337(2), 345 (2009)
  16. Baziar M, Azari A, Karimaei M, Gupta VK, Agarwal S, Sharafi K, Maroosi M, Shariatifar N, Dobaradaran S, J. Mol. Liq., 241, 102 (2017)
  17. Mesdaghinia A, Azari A, Nodehi RN, Yaghmaeian K, Bharti AK, Agarwal S, Gupta VK, Sharafi K, J. Mol. Liq., 233, 378 (2017)
  18. Pera-Titus M, Garcia-Molina V, Banos MA, Gimenez J, Esplugas S, Appl. Catal. B: Environ., 47(4), 219 (2004)
  19. Ye FX, Shen DS, Chemosphere, 54(10), 1573 (2004)
  20. Gupta VK, Jain R, Mittal A, Saleh TA, Nayak A, Agarwal S, Sikarwar S, Mater. Sci. Eng. C-Biomimetic Supramol. Syst., 32(1), 12 (2012)
  21. Saravanan R, Karthikeyan S, Gupta VK, Sekaran G, Narayanan V, Stephen A, Mater. Sci. Eng. C-Biomimetic Supramol. Syst., 33(1), 91 (2013)
  22. Gupta VK, Jain R, Nayak A, Agarwal S, Shrivastava M, Mater. Sci. Eng. C-Biomimetic Supramol. Syst., 31(5), 1062 (2011)
  23. Deng J, Shao Y, Gao N, Deng Y, Tan C, Zhou S, Int. J. Environ. Sci. Technol., 11(4), 881 (2014)
  24. Matzek LW, Carter KE, Chemosphere, 151, 178 (2016)
  25. Wei XY, Gao NY, Li CJ, Deng Y, Zhou SQ, Li L, Chem. Eng. J., 285, 660 (2016)
  26. Zhao J, Zhang Y, Quan X, Chen S, Sep. Purif. Technol., 71(3), 3020 (2010)
  27. Giri S, Bhaumik M, Das R, Gupta VK, Maity A, Appl. Catal. B: Environ., 202, 207 (2017)
  28. Al-Shamsi MA, Thomson NR, Ind. Eng. Chem. Res., 52(38), 13564 (2013)
  29. Mittal A, Ahmad R, Hasan I, Desalination Water Treatment, 57(32), 15133 (2016)
  30. Lin YT, Liang CJ, Yu CW, Ind. Eng. Chem. Res., 55(8), 2302 (2016)
  31. Li X, Zhou MH, Pan YW, Xu LT, Chem. Eng. J., 307, 1092 (2017)
  32. Temiz K, Olmez-Hanci T, Arslan-Alaton I, Environ. Technol., 37(14), 1757 (2016)
  33. Keenan CR, Sedlak DL, Environ. Sci. Technol., 42(4), 1262 (2008)
  34. Noradoun CE, Cheng IF, Environ. Sci. Technol., 39(18), 7158 (2005)
  35. Ghaedi AM, Ghaedi M, Vafaei A, Iravani N, Keshavarz M, Rad M, Tyagi I, Agarwal S, Gupta VK, J. Mol. Liq., 206, 195 (2015)
  36. Fakhri A, Rashidi S, Tyagi I, Agarwal S, Gupta VK, J. Mol. Liq., 214, 378 (2016)
  37. Asfaram A, Ghaedi M, Ghezelbash GR, Dil EA, Tyagi I, Agarwal S, Gupta VK, J. Mol. Liq., 214, 249 (2016)
  38. Maran JP, Priya B, Ultrason. Sonochem., 23, 192 (2015)
  39. Shams M, Dehghani MH, Nabizadeh R, Mesdaghinia A, Alimohammadi M, Najafpoor AA, J. Mol. Liq., 224, 151 (2016)
  40. Englehardt JD, Meeroff DE, Echegoyen L, Deng Y, Raymo FM, Shibata T, Environ. Sci. Technol., 41(1), 270 (2007)
  41. Leupin OX, Hug SJ, Water Res., 39(9), 1729 (2005)
  42. Hussain I, Zhang Y, Huang S, RSC Adv., 4(7), 3502 (2014)
  43. Xu XR, Li XZ, Sep. Purif. Technol., 72(1), 105 (2010)
  44. Hussain I, Zhang YQ, Huang SB, Du XZ, Chem. Eng. J., 203, 269 (2012)