화학공학소재연구정보센터
Applied Surface Science, Vol.441, 156-164, 2018
Annealing temperature dependent reversible wettability switching of micro/nano structured ZnO superhydrophobic surfaces
Superhydrophobic ZnO surfaces with reversibly tunable wettability were fabricated on stainless steel meshes via a facile chemical bath deposition method just by regulating the micro/nano structured ZnO needles without using chemical post modifications. The obtained surfaces can be easily and reversibly switched between superhydrophobic and superhydrophilic/underwater superoleophobic characteristics by altering the annealing temperatures. As-prepared sample exhibited long-term superhydrophobic properties with a water contact angle (WCA) of 163.8 degrees +/- 1.8 degrees and contact angle hysteresis (CAH) of 1.1 degrees not approximate to +/- 0.8 degrees. The SEM, XRD, XPS and Raman analyses were employed to characterize the morphological features and surface chemistry of the prepared samples. SEM images showed the formation of ZnO micro/nanoneedles with a diameter of similar to 90 nm on the substrate. The superhydrophobic ZnO surface was switched to highly hydrophilic and underwater superoleophobic properties with an oil contact angle (OCA) of about 172.5 degrees after being annealed at 400 degrees C in air for 30 min and restored to superhydrophobic state again by altering the annealing temperature to 150 degrees C. Mechanical durability of the ZnO superhydrophobic surface was tested by an abrasion test. Results confirmed that the prepared surface exhibited an excellent robustness after 20 abrasion cycles under the pressure of 4.7 kPa. (C) 2018 Elsevier B.V. All rights reserved.