Copper nanowires (Cu NWs) encapsulated with polypyrrole (PPy) (Cu@PPy) have been fabricated by a facile liquid-phase reduction with copper (II) chloride as precursor. The as-synthesized Cu NWs grow along the crystal orientation of (110) and the encapsulated polypyrrole layer is also observed on the surface of Cu NWs. The Cu@PPy nanostructure is investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), and Fourier transform infrared spectroscopy (FTIR). And the experimental results show that the synthesized Cu@PPy are uniform and cross each other with the average width of 160 nm. Additionally, the results of XRD and XPS indicate the Cu@PPy nanostructure has excellent oxidation resistance and temporal stability. (C) 2018 Elsevier B.V. All rights reserved.