Lithium is used in a variety of everyday objects. The most important field of application is as components of battery electrolytes and electrodes. Next to salar brines, commercial lithium production relies on mineral ore sources such as spodumene, petalite, and lepidolite. This study provides an economic comparison of two processes for the extraction of lithium from zinnwaldite concentrate, a lithium mineral that can be found along the Czech/German border at Cinovec/Zinnwald. In contrast to the state-of-the-art lithium extraction from siliceous ores, which is a hydrometallurgical extraction process with sulfuric acid, the novel direct-carbonation process is based on digestion using supercritical carbon dioxide. An assessment of the capital and operating expenditures was also carried out.