Most of the time char particles in commercial FB units encounter considerably lower oxygen concentrations than that in the entrance, say between 2% and 10%, and the effects of the oxy-fuel atmosphere on the conversion history of char particles need to be clearly treated under these conditions. In the present work, an experimental study of combustion of bituminous coal char was carried out in a laboratory FB in O-2/CO2 and O-2/N-2 atmospheres under simulated FB combustor conditions at O-2 concentrations of 4-10% v/v, bed temperatures of 800-900 degrees C and char particle sizes of 2-8mm by continuously measuring the concentrations of O-2 and CO in the flue gas. The results indicate that the conversion of char is controlled by diffusion of O-2 in the boundary layer of the particle in O-2/CO2 and O-2/N-2 environments and that the gasification of char in O-2/CO2 is limited by chemical kinetics. A char conversion model, taking into account the mass transfer from the bed to the particle and the gasification kinetics of char, was built, based on the experimental results and the intrinsic reactivity of char obtained in TGA tests. Simulations, carried out under the same conditions as in the FB experiments, give good agreement in terms of burnout time and instantaneous reactivity during the conversion of single particles. Simulated results prove that the low diffusivity of O-2 in CO2 is the main reason for the decreased reaction rate of the char particle in O-2/CO2 compared with O-2/N-2. The contribution of gasification to the consumption of char is more notable at high bed temperature (900 degrees C) and coarse particles (8 mm), particularly at lower oxygen concentration (4-6% v/v).