화학공학소재연구정보센터
Chemical Physics Letters, Vol.692, 38-43, 2018
Heat-induced morphological transformation of gold nanodumbbells in ionic surfactant solutions
The thermal stability of gold nanodumbbells (NDs) is studied in aqueous solution of ionic surfactants. It is found in aqueous solution of cetyltrimethylammonium bromide that the blue-shift of longitudinal surface plasmon resonance band of gold NDs occurs at 75 degrees C and the new gold nanorods (NRs) with shortened aspect ratio are formed at the same time. The aspect ratio of the generated gold NRs gradually decreases and finally approaches similar to 1.7 after repeated processing. Similarly, the same results are also obtained in aqueous solution of sodium dodecyl sulfate at room temperature. Mechanism is proposed for the shape transformation of gold NDs. (C) 2017 Elsevier B.V. All rights reserved.