Chemistry Letters, Vol.47, No.2, 247-250, 2018
Effect of Polycaprolactone Crystalline Block on Surface Reorganization of a Phosphorylcholine-based Amphiphilic Block Copolymer Surface Modifier
The surface reorganization behavior of a crystalline ABCBA-type copolymer and a non-crystalline ABA-type copolymer including poly(2-methacryloyloxyethyl phosphorylcholine) was investigated. The crystalline domain in the block copolymer suppressed the surface reorganization when exposed to either hydrophilic or hydrophobic condition.