A new hybrid hierarchical porous Co(OH)F/Ni(OH)(2) for supercapacitors was fabricated via one-pot hydrothermal method. X-ray diffraction (XRD) revealed that the Co(OH)F/Ni(OH)(2) (Co/Ni = 3:1) hybrid was composed of orthorhombic Co(OH)F and hexagonal Ni(OH)(2) phases. X-ray photoelectron spectra (XPS) illustrated the presence of O1s, F1s, Co2p and Ni2p for the Co(OH) F/Ni(OH)(2) (Co/Ni = 3:1) hybrid. The scanning/transmission electron microscopy (SEM/TEM) showed that the Co(OH) F/Ni(OH)(2) (Co/Ni = 3:1) hybrid exhibited the morphology of both the nanorods of bare Co(OH) F and nanoflakes of bare Ni(OH)(2). The energy dispersive spectrometry (EDS) and mapping results showed the Co/Ni ratio of 3.1:1 and uniform distributions of O, F, Co and Ni elements of the Co(OH)F/Ni(OH)(2) (Co/Ni = 3:1) hybrid. Nitrogen sorption measurements suggest the hierarchical porous structure of the Co(OH)F/Ni(OH)(2) (Co/Ni = 3:1) hybrid. The Co(OH)F/Ni(OH)(2) (Co/Ni = 3:1) hybrid showed the more attractive electrochemical performance than the other Co(OH)F/Ni(OH)(2) candidates (Co/Ni = 1:0, 1:1, 1:3, 0:1) due to the stronger synergistic effect of Co and Ni redox species, exhibiting high specific capacity and rate behavior (10498 C g(-1) at 1-16 A g(-1)) together with excellent cycling stability (116% retention/5000 cycles/6 A g(-1)). Furthermore, the designed activated carbon (AC)//Co(OH)F/Ni(OH)(2) (Co/Ni = 3:1) asymmetric capacitor exported both high energy and power densities (13.8-8 Wh kg(-1)/0.53-4.7 kW kg(-1)) along with excellent cycle life (121% retention/10,000 cycles/4 A g(-1)), showing the superior performance than the other AC//Co(OH)F/Ni(OH)(2) capacitors (Co/Ni = 1:0, 1:1, 1:3, 0:1). (C) 2018 Elsevier Ltd. All rights reserved.