A recently developed spatially resolved X-ray diffraction (SRXRD) technique utilizing intense synchrotron radiation has been refined to yield phase and microstructural information down to 200 mu m in spatial extent in materials subjected to steep thermal gradients during processing. This SRXRD technique has been applied to map completely the phases and their solid-state transformation in the so-called heat-affected zone (HAZ) in titanium fusion welds in situ during the welding process. Detailed profile analysis of the SRXRD patterns revealed four principal microstructural regions at temperature in the vicinity of the HAZ surrounding the liquid weld pool: (i) a completely transformed beta-Ti zone 2-3 mm adjacent to the liquid weld pool; (ii) a mixed alpha+beta-Ti region surrounding the pure beta-Ti zone, (iii) a back-transformed alpha-Ti zone on the backside of the HAZ where pure beta-Ti once existed at temperature well above the alpha --> beta transformation isotherm, and (iv) a more diffused region outside the HAZ where annealing and recrystallization of the alpha-Ti base metal occur. The high-temperature microstructures so derived corroborate well the expected transformation kinetics in pure titanium, and the observed phase transformation boundaries are in good agreement with those predicted from the transformation isotherms calculated from a simplified heat-flow model. Based on a detailed assessment of the SRXRD setup employed, improved experimentations such as a smaller beam spot emitted from third generation synchrotron sources, better mechanical stability (tighter scattering geometry), and use of an area detector would enable more quantitative structural information for future phase dynamics studies exemplified by this work.