The main objective of this study is the investigation of the effect of the optical path of incident beam solar radiation on the performance of a linear Fresnel concentrating solar collector. The requirements regarding the kinematics of the reflectors are examined, allowing the effective focus of the reflected radiation on the receiver cover. A methodology for the calculation of the reflection angles of the sun rays incident on the mirrors, as well as of the incidence angles of the reflected rays on the cover, as a function of the sun position and the geometry of the collector is proposed. Specific scenarios, describing the effect of the solar radiation optical path on the collected heat, are formulated, each of them leading to a different form for the instantaneous efficiency equation. The evaluation and analysis of these scenarios, on the basis of actual operation conditions, has shown that the effect of the reflection and incidence angles throughout the modeling of the collector and the calculation of the useful thermal power cannot be neglected.