The hydrogen storage capacity and performance of Ca and K decorated germanene were studied using density functional theory calculation. The Ca and K adatoms were found to be sufficiently bonded to the germanene without clustering at the hollow site. Further investigation has shown an ionic bonding is apparent based on the charge density difference and Bader charge analysis. Upon adsorption of H-2 on the decorated germanene, it was found that the Ca and K decorated systems could adsorb 8 and 9 H-2 molecules, respectively. The adsorption energies of H-2 molecules were within the Van der Waals energy (400-435 meV), suggesting weak physisorption. The charge density profile revealed that the electron of H-2 moved toward the adatom decoration without leaving the local region of H-2. This suggests that a dipole-dipole interaction was apparent and consistent with the energy range found. Finally, the gravimetric density obtained from the adsorption of H-2 on the decorated germanene shows that this material is a potential for H-2 storage media. (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.