In present study, new strategy is employed to build composite nanostructure and asymmetric configuration to enhance the capacitive performance of supercapacitor device. The WO3-MnO2 composite with mesoporous structure is prepared by single-step hydrothermal method and used to gain superior electrochemical performance in asymmetric configuration. A binder-free and additive-less WO3-MnO2 composite electrode exhibits high specific capacitance of 609 F g(-1) at a scan rate of 5 mV s(-1). The flexible asymmetric supercapacitor device with WO3-MnO2 as a positive electrode and WO3 as a negative electrode demonstrates stable operating potential window of 1.4 V with specific capacitance of 103 F g(-1) at a scan rate of 5 mV s(-1) and energy density of 24.13 Wh kg(-1) at power density of 915 W kg(-1). Furthermore, WO3-MnO2//WO3 device exhibits good cycle life with capacity retention of 95% after 2500 cycles and excellent mechanical flexibility. These results reveal the potential of WO3-MnO2 composite electrode for fabrication of highperformance supercapacitors. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.